Determine the effectiveness factor for the spherical

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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### Understanding Catalyst Effectiveness in Chemical Reactions

1. **Diffusion and Catalyst Pellets:**  
   If the internal diffusion resistance of the catalyst pellet is small, meaning the diffusion within the pellet is fast enough to be uniform throughout at the concentration outside the pellet, the reaction rate can be defined using the following equation:
   
   \[
   \text{Rate} = -\frac{4}{3} \pi a^3 k C_o
   \]

   In this equation:
   - \( a \) represents the radius of the spherical pellet.
   - \( k \) is the reaction rate constant.
   - \( C_o \) is the concentration outside the pellet.

2. **Effectiveness Factor:**  
   The ratio of this reaction rate to another reaction rate is referred to as the **effectiveness factor**. It is crucial to determine the effectiveness factor for the spherical pellet to understand how efficiently a catalyst is being used in a reaction.

### Practical Application
Students and professionals in chemical engineering can apply these concepts to evaluate catalyst efficiency. By calculating the effectiveness factor, one can optimize the design and operation of catalytic reactors, ensuring processes are both economical and efficient.
Transcribed Image Text:### Understanding Catalyst Effectiveness in Chemical Reactions 1. **Diffusion and Catalyst Pellets:** If the internal diffusion resistance of the catalyst pellet is small, meaning the diffusion within the pellet is fast enough to be uniform throughout at the concentration outside the pellet, the reaction rate can be defined using the following equation: \[ \text{Rate} = -\frac{4}{3} \pi a^3 k C_o \] In this equation: - \( a \) represents the radius of the spherical pellet. - \( k \) is the reaction rate constant. - \( C_o \) is the concentration outside the pellet. 2. **Effectiveness Factor:** The ratio of this reaction rate to another reaction rate is referred to as the **effectiveness factor**. It is crucial to determine the effectiveness factor for the spherical pellet to understand how efficiently a catalyst is being used in a reaction. ### Practical Application Students and professionals in chemical engineering can apply these concepts to evaluate catalyst efficiency. By calculating the effectiveness factor, one can optimize the design and operation of catalytic reactors, ensuring processes are both economical and efficient.
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