Decomposition of ozone to oxygen occurs as a series of radical reactions. The Individual reactions in this series are listed below but they are not in the correct order. Use the labels on the right to correct the order of the reactions. 1st 3rd 5th 2nd 4th CIOO Cl• + 0₂ - 2 Cl. +203->> CIOOCI CI F-C-Cl F UV photon 2 CIQ. +20₂ ►CIOO + Cl CI 1 F-C+Cl UV photon A 220 nm 2 CIO- -CIOOCI F

2. Use the graph provided in Example 14.1 to estimate the average rate of disappearance of dye for the period 1-3 minutes. 0.6 mol/L · min 1.2 × 10−5 mol/L · min 0.6 × 10−5 mol/l · min 1.2 mol/L · min

The acid-catalyzed iodination of acetone CH3COCH3(aq) + I2(aq) CH3COCH2I(aq) + HI(aq) is a common laboratory experiment used in general chemistry courses to teach the method of initial rates. The reaction is followed spectrophotometrically by the disappearance of the color of iodine in the solution. The following data (J. P. Birk and D. L Walters, Journal of Chemical Education, Vol. 69, p. 585, 1992) were collected at 23 C for this reaction. Determine the rate law for this reaction.

The following experimental data were obtained for the reaction of \'I14* and NOf in acidic solution. NH/(aq) + NO2-(aq) — N;(g) + 2 H,O(f) INH/I (mol L1) [NO21 (mol L-1, Rate = A[NJ/At (mol L-1 s’) 0.0092 0.098 3.33 X IO"7 0.0092 0.049 1.66 X 10‘7 0.0488 0.196 3.51 X 10"6 0.0249 0.196 1.80 X 10-6 Determine the rate law for this reaction and calculate the rate constant.

Define stability from both a kinetic and thermodynamic perspective. Give examples to show the differences in these concepts.

Consider a reaction of the type aA products, in which the rate law is found to he rate = k[A]3 (termolecular reactions are improbable but possible). If the first half-tife of the reaction is found to he 40. s, what is the time for the second half-life? Hint: Using your calculus knowledge, derive the integrated rate law from the differential rate law for a tennolecular reaction: Rate=d[A]dt=k[A]3

please answer all parts

но HO Но HO co + ½ 0, - + H,O H" H но Он ascorbic acid dehydroascorbic acid Vitamin C is oxidized slowly to dehydroascorbic acid by the oxygen in air. It is catalyzed by ions such as Cu*2 and Fe*3. The reaction can be followed by measuring the ultraviolet absorbance at 243 nm. Time (hours) Absorbance (A) 1/A In A - In A 0.75 1.3 -0.29 0.29 1 0.38 2.6 -0.97 0.97 0.19 5.3 - 1.7 1.7 3 0.095 11 - 2.4 2.4 27. Which of the following is the best interpretation of the data given above? (A) The data support a zero-order reaction. (B) The data support a first-order reaction. (C) The data support a second-order reaction. (D) The overall order is third. 28. A new compound is synthesized and found to be a monoprotic acid with a molar mass of 248 g/mole. When 0.0050 moles of this acid are dissolved in 0.500L of water, the pH is measured as 2.94. What is the pk, of this acid? (A) (В) (C) (D) 2.33 3.89 5.78 7.78 29. What is the hybridization of carbon 1 (far left) and carbon 2 (middle) in this…

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Remaining Time: 58 minutes, 17 seconds. * Question Completion Status: Study the reaction below and indicate which product will not formed in the reaction. OH of KMNO, OH H20. OH B OA.A O B. B O C. Both A and B will be formed D. None of the products will be formed es A Moving to the next question prevents changes to this answer. 4, Unit 4- Diastereo.m4v Open fls 3. Unit 4 - RAnd S.m4v 1. Unit 4 - Introduct.m4v Open file Open file 2. Ur Ope search a 99. %23 A ort