Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
problem d please
Transcribed Image Text:Stereochemistry. Give the structure and predict the stereochemistry of the major
product formed in each of the following reactions. Give an explanation for your
choice of stereochemistry.
a.
b.
C.
d.
Me
t-Bu
HO
Me
OH
Me
Me
1. Ti(Oi-Pr)4, (+)-DET
TBHP, CH₂Cl₂
2. H₂C=CHCH₂MgCl
THF
CO₂K
OBPS
a. BH3, THF
b. NaOH, H₂O2
OBn
1. Ti(O+-Pr)4
B
(-)-DET, t-BuOOH
CH₂Cl2, -20 °C
2. Red-AI, THF, rt
A1
1. 12, CH3CN, -15 °C
2. BnOK, THF, -20 °C
►D
3. (MeO)2CMe2
cat. H+
4a. O3, EtOH, -78 °C
4b. Me₂S, NaBH4
с
A2
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