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Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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CHE154-H Gen Chem II Bronikowski S20
<CHE154 S20 Ch18 Sec4-6
Chapter 18 Algorithmic Question 60
Part A
A 25.0 mL sample of 0.150 M benzoic acid is titrated with a 0.150M NaOH solution. What is the pH at the equivalence point? The K of benzoic acid is 6.5 x 10.
11.20
4.20
9.80
7.20
8.53
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Step 1
Given,
Volume of benzoic acid = 25.0 mL = 0.025 L (1 mL = 0.001 L)
Molarity of benzoic acid = 0.150 M = 0.150 mol/L
Molarity of NaOH = 0.150 M = 0.150 mol/L
Ka = 6.5 × 10-5
Step 2
Moles of benzoic acid can be calculated as :
Step 3
The reaction of benzoic acid with strong base, NaOH can be written as :
C6H5COOH (aq) + OH- (aq) → C6H5COO- (aq) + H2O (l)
At equivalence point, the moles of benzoic acid will be equal to the moles of NaOH. Thus, we can calculate the volume of NaOH used as :
Step 4
At equivalence point, the concentration of C6H5COO- will be :
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