d) The reaction 2NO, (g) 2NO (g) + 02 (g) has the rate constantk = 0.63 M-'s. i. Determine the order of the reaction in NO2. ii. If the initial concentration of NO2 is 0.050M, determine the concentration of this reactant after 0.50 hours. ii. The NO in the above reaction is used to produce nitrosyl chloride (NOCI) as shown below: 2NO (g) + Cl, (g) 2NOCI (g) The following data was then obtained. (under conditions of constant [Cl,]) Time Determine if the following mechanism is consistent with the data. Explain your answer. NO (g) + Cl, (g) NOCI, (g) (fast) NOCI, (g) + NO (g) 2NOCI (g) (slow) IONI/I

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d) The reaction
2NO, (g)
2NO (g) + 02 (g)
has the rate constantk = 0.63 M's1.
i.
Determine the order of the reaction in NO2.
ii.
If the initial concentration of NO2 is 0.050M, determine the concentration of this
reactant after 0.50 hours.
ii.
The NO in the above reaction is used to produce nitrosyl chloride (NOCI) as shown
below:
2NO (g) + Cl, (g)
2NOCI (g)
The following data was then obtained.
(under conditions of constant [Cl,])
Time
Determine if the following mechanism is consistent with the data. Explain your answer.
NO (g) + Cl, (g)
NOCI, (g)
(fast)
NOCI, (g) + NO (g)
2NOCI (g)
(slow)
1/[NO]
Transcribed Image Text:d) The reaction 2NO, (g) 2NO (g) + 02 (g) has the rate constantk = 0.63 M's1. i. Determine the order of the reaction in NO2. ii. If the initial concentration of NO2 is 0.050M, determine the concentration of this reactant after 0.50 hours. ii. The NO in the above reaction is used to produce nitrosyl chloride (NOCI) as shown below: 2NO (g) + Cl, (g) 2NOCI (g) The following data was then obtained. (under conditions of constant [Cl,]) Time Determine if the following mechanism is consistent with the data. Explain your answer. NO (g) + Cl, (g) NOCI, (g) (fast) NOCI, (g) + NO (g) 2NOCI (g) (slow) 1/[NO]
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