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(d) The overall reaction A + B = C + D has a mechanism in elementary reactions given below, with rate coefficients indicated. X is a reactive intermediate. A + B X + C k1 X + B k2 X + C A + B k3 Derive an expression for the rate of formation of product D in terms of rate coefficients and reactant or product concentrations only. Simplify this expression under conditions of k2[B] >> k3[C] and k2[B] << k3[C].

(d) The overall reaction A + B = C + D has a mechanism in elementary reactions given below, with rate coefficients indicated. X is a reactive intermediate. A + B X + C k1 X + B k2 X + C A + B k3 Derive an expression for the rate of formation of product D in terms of rate coefficients and reactant or product concentrations only. Simplify this expression under conditions of k2[B] >> k3[C] and k2[B] << k3[C].

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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(d) The overall reaction A + B = C + D has a mechanism in elementary reactions given below, with rate coefficients indicated. X is a reactive intermediate. A + B X + C k1 X + B D k2 X + C A + B k3 Derive an expression for the rate of formation of product D in terms of rate coefficients and reactant or product concentrations only. Simplify this expression under conditions of k2[B] >> k3[C] and k2[B] << k3[C].
Transcribed Image Text:(d) The overall reaction A + B = C + D has a mechanism in elementary reactions given below, with rate coefficients indicated. X is a reactive intermediate. A + B X + C k1 X + B D k2 X + C A + B k3 Derive an expression for the rate of formation of product D in terms of rate coefficients and reactant or product concentrations only. Simplify this expression under conditions of k2[B] >> k3[C] and k2[B] << k3[C].
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