d) For the electrochemical cell Cr(s) | Cr2O72-(aq) || Cu²*(aq) | Cu(s) the two half reactions have standard reduction potentials at 298 K of Cr2072-(aq) + 14H*(aq) + 12e- → 2Cr(s) + 7H2O(1) = 0.310 V %3D Cu2*(aq) + 2e- → Cu(s) = 0.339 V %3D i) Write down the overall reaction for this cell and determine the standard cell potential at 298 K. ii) Calculate the equilibrium constant for this reaction at 298 K.
d) For the electrochemical cell Cr(s) | Cr2O72-(aq) || Cu²*(aq) | Cu(s) the two half reactions have standard reduction potentials at 298 K of Cr2072-(aq) + 14H*(aq) + 12e- → 2Cr(s) + 7H2O(1) = 0.310 V %3D Cu2*(aq) + 2e- → Cu(s) = 0.339 V %3D i) Write down the overall reaction for this cell and determine the standard cell potential at 298 K. ii) Calculate the equilibrium constant for this reaction at 298 K.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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![d) For the electrochemical cell
Cr(s) | Cr2O72-(aq) || Cu²*(aq) | Cu(s)
the two half reactions have standard reduction potentials at 298 K of
Cr2072-(aq) + 14H*(aq) + 12e- → 2Cr(s) + 7H2O(1)
E® = 0.310 V
%3D
Cu2*(aq) + 2e--
Cu(s)
= 0.339 V
%D
i) Write down the overall reaction for this cell and determine the
standard cell potential at 298 K.
ii) Calculate the equilibrium constant for this reaction at 298 K.
e) The standard potential of an electrochemical cell has been measured at
several different temperatures.
T/°C
-10
40
90
120
E° / V
0.261
0.269
0.324
0.388
0.421
From these data, determine the values of A.GR, A.SR and A:HA for the
reaction at 20 °C given that the number of electrons in the balanced half
reactions is one.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff4034ead-a81c-474d-bc26-2bb6a2dec46f%2F65f5b026-d9d6-48a0-ac0d-e58b5adca1d0%2Fex0jzwx_processed.png&w=3840&q=75)
Transcribed Image Text:d) For the electrochemical cell
Cr(s) | Cr2O72-(aq) || Cu²*(aq) | Cu(s)
the two half reactions have standard reduction potentials at 298 K of
Cr2072-(aq) + 14H*(aq) + 12e- → 2Cr(s) + 7H2O(1)
E® = 0.310 V
%3D
Cu2*(aq) + 2e--
Cu(s)
= 0.339 V
%D
i) Write down the overall reaction for this cell and determine the
standard cell potential at 298 K.
ii) Calculate the equilibrium constant for this reaction at 298 K.
e) The standard potential of an electrochemical cell has been measured at
several different temperatures.
T/°C
-10
40
90
120
E° / V
0.261
0.269
0.324
0.388
0.421
From these data, determine the values of A.GR, A.SR and A:HA for the
reaction at 20 °C given that the number of electrons in the balanced half
reactions is one.
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