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Cyclopropane isomerizes into propene when heated to 500°C in the gas phase. The extent of conversion was followed by gas chromatography by allowing the reaction to proceed for a time with various initial pressures: Po/Torr t/s 200 200 400 400 600 600 100 200 100 200 100 200 pr 186 173 373 347 559 520 where p, is the initial pressure of cyclopropane and pr the pressure of cyclopropane after t seconds. What is the order of the reaction and the value of the rate constant for the reaction under these conditions? (NOTE: px (nx/V)*RT = [X]*RT, so you can use pressure-rather than concentration-in the rate law equations.

Cyclopropane isomerizes into propene when heated to 500°C in the gas phase. The extent of conversion was followed by gas chromatography by allowing the reaction to proceed for a time with various initial pressures: Po/Torr t/s 200 200 400 400 600 600 100 200 100 200 100 200 pr 186 173 373 347 559 520 where p, is the initial pressure of cyclopropane and pr the pressure of cyclopropane after t seconds. What is the order of the reaction and the value of the rate constant for the reaction under these conditions? (NOTE: px (nx/V)*RT = [X]*RT, so you can use pressure-rather than concentration-in the rate law equations.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Cyclopropane isomerizes into propene when heated to 500°C in the gas phase. The extent of conversion was followed by gas chromatography by allowing the reaction to proceed for a time with various initial pressures: Po/Torr t/s 200 200 400 400 600 600 100 200 100 200 100 200 Pr 186 173 373 347 559 520 where is the order of the reaction and the value of the rate constant for the reaction under these conditions? (NOTE: px = (nxV)*RT = [X]*RT, so you can use pressure-rather than concentration-in the rate law equations.) P. is the initial pressure of cyclopropane and p, the pressure of cyclopropane after t seconds. What
Transcribed Image Text:Cyclopropane isomerizes into propene when heated to 500°C in the gas phase. The extent of conversion was followed by gas chromatography by allowing the reaction to proceed for a time with various initial pressures: Po/Torr t/s 200 200 400 400 600 600 100 200 100 200 100 200 Pr 186 173 373 347 559 520 where is the order of the reaction and the value of the rate constant for the reaction under these conditions? (NOTE: px = (nxV)*RT = [X]*RT, so you can use pressure-rather than concentration-in the rate law equations.) P. is the initial pressure of cyclopropane and p, the pressure of cyclopropane after t seconds. What
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