Using the calculated results in the picture attached, starting at 15 minutes, calculate the rate constants, k (last column in the data sheet). Then calculate the average value of k. Use the following equation to help calculate: ln (a/a0) = -kt

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter2: Basic Statistical Analysis With Excel
Section: Chapter Questions
Problem 12P
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Using the calculated results in the picture attached, starting at 15 minutes, calculate the rate constants, k (last column in the data sheet). Then calculate the average value of k. Use the following equation to help calculate: ln (a/a0) = -kt

Time Elapsed
(min)
20°C:
ONGKERS S
0
5
10
20
25
30
40
30°C:
0
5.
10
15
20
25
-30
35
40°
Gas Buret
Vol O₂ (in mL; (V - V) x (a)
Reading (mL) H₂O-corrected -
reading).
10.81
15.01
19.28
22.47
25.69
28.38
30.58
32.56
31.75
34.37 33.51
49.49 48.25
10.54 37.71
14.63
18.80
21.91
25.05
27.67
29.82
35.45
37.89
12.80
12.48
21.02 20:49
27.33
26.65
31.90
40.01
41.68
42-83
33.62
29.45
26.34
23.20
20.58
40.64
41.76
48.39 47.18
18.43
16.50
39.0561 8.17
-=(ª)
a
V-V. (a)
34.70
26.69.
20.53
31.10
16.08
34.56 12.62 0.3637
36-94
V. - Vt
O
In
2
a
14.74 0.3909 -0.9393
s
(20)
1.0000
O
0.8915 -0.1149.
0.7810 -0.2472
0.6985 -0.3588
0.6152 -0.4858
6.5457 -0.6057
0.4887 -0.7160
0.4376 -0.8265
10.24 0.2951 -1.2204
1.0000
O
0.7692 -0.2624
0.5916
-0.5250
0.4634 -0-7692
0.3637 -1.0114
6.54 0.1885
0.1885-16687
5.42 0.1562 -1.8566
O
k(min-1)
from Eq.[3-4]
0.2354 -1.4465
Transcribed Image Text:Time Elapsed (min) 20°C: ONGKERS S 0 5 10 20 25 30 40 30°C: 0 5. 10 15 20 25 -30 35 40° Gas Buret Vol O₂ (in mL; (V - V) x (a) Reading (mL) H₂O-corrected - reading). 10.81 15.01 19.28 22.47 25.69 28.38 30.58 32.56 31.75 34.37 33.51 49.49 48.25 10.54 37.71 14.63 18.80 21.91 25.05 27.67 29.82 35.45 37.89 12.80 12.48 21.02 20:49 27.33 26.65 31.90 40.01 41.68 42-83 33.62 29.45 26.34 23.20 20.58 40.64 41.76 48.39 47.18 18.43 16.50 39.0561 8.17 -=(ª) a V-V. (a) 34.70 26.69. 20.53 31.10 16.08 34.56 12.62 0.3637 36-94 V. - Vt O In 2 a 14.74 0.3909 -0.9393 s (20) 1.0000 O 0.8915 -0.1149. 0.7810 -0.2472 0.6985 -0.3588 0.6152 -0.4858 6.5457 -0.6057 0.4887 -0.7160 0.4376 -0.8265 10.24 0.2951 -1.2204 1.0000 O 0.7692 -0.2624 0.5916 -0.5250 0.4634 -0-7692 0.3637 -1.0114 6.54 0.1885 0.1885-16687 5.42 0.1562 -1.8566 O k(min-1) from Eq.[3-4] 0.2354 -1.4465
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