cry 23.26 Indicate the coordination number and the oxidation num. ber of the metal for each of the following complexes: (a) K3[Co(CN)6] (b) Na[CdBr4] (c) [Pt(en)3](Cl04)4 (d) [Co(en)2(C204)]* (e) NH4[Cr(NH3)2(NCS)4] (f) [Cu(bipy)2I]I Common Ligands in Coordination Chemistry Section 23.3) 23.27 For each of the following molecules or polyatomic ions, draw the Lewis structure and indicate if it can act as a monodentate ligand, a bidentate ligand, or is unlikely to act as a ligand at all: (a) ethylamine, CH,CH,NH, (b) trimethylphosphine, P(CH,)3, (c) carbonate, CO,2- ale (d) ethane, C,H, 23.28 For each of the following polydentate ligands, determine (1) ph the maximum number of coordination sites that the ligand can occupy on a single metal ion and (ii) the number and type of donor atoms in the ligand: (a) ethylenediamine (en), (b) bipyridine (bipy), (c) the oxalate anion (C2O4), (d) the 2- ion of the porphine molecule (Figure 23.13), (e) [EDTA]4. 3.29 Polydentate ligands can vary in the number of coordi- nation positions they occupy. In each of the following, identify the polydentate ligand present and indicate the probable number of coordination positions it orcunies: Z8.3
cry 23.26 Indicate the coordination number and the oxidation num. ber of the metal for each of the following complexes: (a) K3[Co(CN)6] (b) Na[CdBr4] (c) [Pt(en)3](Cl04)4 (d) [Co(en)2(C204)]* (e) NH4[Cr(NH3)2(NCS)4] (f) [Cu(bipy)2I]I Common Ligands in Coordination Chemistry Section 23.3) 23.27 For each of the following molecules or polyatomic ions, draw the Lewis structure and indicate if it can act as a monodentate ligand, a bidentate ligand, or is unlikely to act as a ligand at all: (a) ethylamine, CH,CH,NH, (b) trimethylphosphine, P(CH,)3, (c) carbonate, CO,2- ale (d) ethane, C,H, 23.28 For each of the following polydentate ligands, determine (1) ph the maximum number of coordination sites that the ligand can occupy on a single metal ion and (ii) the number and type of donor atoms in the ligand: (a) ethylenediamine (en), (b) bipyridine (bipy), (c) the oxalate anion (C2O4), (d) the 2- ion of the porphine molecule (Figure 23.13), (e) [EDTA]4. 3.29 Polydentate ligands can vary in the number of coordi- nation positions they occupy. In each of the following, identify the polydentate ligand present and indicate the probable number of coordination positions it orcunies: Z8.3
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter21: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 2RQ
Related questions
Question
26: d,e,f
![cry
23.26 Indicate the coordination number and the oxidation num.
ber of the metal for each of the following complexes:
(a) K3[Co(CN)6]
(b) Na[CdBr4]
(c) [Pt(en)3](Cl04)4
(d) [Co(en)2(C204)]*
(e) NH4[Cr(NH3)2(NCS)4]
(f) [Cu(bipy)2I]I
Common Ligands in Coordination Chemistry
Section 23.3)
23.27 For each of the following molecules or polyatomic ions,
draw the Lewis structure and indicate if it can act as a
monodentate ligand, a bidentate ligand, or is unlikely
to act as a ligand at all: (a) ethylamine, CH,CH,NH,
(b) trimethylphosphine, P(CH,)3, (c) carbonate, CO,2-
ale
(d) ethane, C,H,
23.28 For each of the following polydentate ligands, determine (1)
ph the maximum number of coordination sites that the ligand
can occupy on a single metal ion and (ii) the number and
type of donor atoms in the ligand: (a) ethylenediamine
(en), (b) bipyridine (bipy), (c) the oxalate anion (C2O4),
(d) the 2- ion of the porphine molecule (Figure 23.13),
(e) [EDTA]4.
3.29 Polydentate ligands can vary in the number of coordi-
nation positions they occupy. In each of the following,
identify the polydentate ligand present and indicate the
probable number of coordination positions it orcunies:
Z8.3](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb2f71cc3-406d-4549-a751-96d454552a8c%2F5dbacfdd-d13d-45b6-aa2f-b52384ef8036%2Fw2bib40a.jpeg&w=3840&q=75)
Transcribed Image Text:cry
23.26 Indicate the coordination number and the oxidation num.
ber of the metal for each of the following complexes:
(a) K3[Co(CN)6]
(b) Na[CdBr4]
(c) [Pt(en)3](Cl04)4
(d) [Co(en)2(C204)]*
(e) NH4[Cr(NH3)2(NCS)4]
(f) [Cu(bipy)2I]I
Common Ligands in Coordination Chemistry
Section 23.3)
23.27 For each of the following molecules or polyatomic ions,
draw the Lewis structure and indicate if it can act as a
monodentate ligand, a bidentate ligand, or is unlikely
to act as a ligand at all: (a) ethylamine, CH,CH,NH,
(b) trimethylphosphine, P(CH,)3, (c) carbonate, CO,2-
ale
(d) ethane, C,H,
23.28 For each of the following polydentate ligands, determine (1)
ph the maximum number of coordination sites that the ligand
can occupy on a single metal ion and (ii) the number and
type of donor atoms in the ligand: (a) ethylenediamine
(en), (b) bipyridine (bipy), (c) the oxalate anion (C2O4),
(d) the 2- ion of the porphine molecule (Figure 23.13),
(e) [EDTA]4.
3.29 Polydentate ligands can vary in the number of coordi-
nation positions they occupy. In each of the following,
identify the polydentate ligand present and indicate the
probable number of coordination positions it orcunies:
Z8.3
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 3 steps with 6 images
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry: An Atoms First Approach](https://www.bartleby.com/isbn_cover_images/9781305079243/9781305079243_smallCoverImage.gif)
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781133611097/9781133611097_smallCoverImage.gif)
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry: An Atoms First Approach](https://www.bartleby.com/isbn_cover_images/9781305079243/9781305079243_smallCoverImage.gif)
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781133611097/9781133611097_smallCoverImage.gif)
![Chemistry & Chemical Reactivity](https://www.bartleby.com/isbn_cover_images/9781337399074/9781337399074_smallCoverImage.gif)
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
![Chemistry & Chemical Reactivity](https://www.bartleby.com/isbn_cover_images/9781133949640/9781133949640_smallCoverImage.gif)
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
![Chemistry: The Molecular Science](https://www.bartleby.com/isbn_cover_images/9781285199047/9781285199047_smallCoverImage.gif)
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning