Consider this reaction: 280, (g) → 2S0, (g) + O, (g) At a certain temperature it obeys this rate law. rate = (0.0149 s1)[so,] Suppose a vessel contains SO, at a concentration of 1.30M. Calculate the concentration of SO, in the vessel 62.0 seconds later. You may assume no other reaction is important. Round your answer to 2 significant digits.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
### Reaction Rate and Concentration Calculation

Consider the following reaction:

\[ 2SO_3 (g) \rightarrow 2SO_2 (g) + O_2 (g) \]

At a certain temperature, this reaction follows the rate law given by:

\[ \text{rate} = (0.0149 \, s^{-1})[SO_3] \]

#### Problem Statement

Suppose a vessel contains \( SO_3 \) at a concentration of \( 1.30 \, M \). Calculate the concentration of \( SO_3 \) in the vessel after 62.0 seconds. You may assume no other reaction is important. Round your answer to 2 significant digits.

#### Solution

To calculate the concentration of \( SO_3 \) after a given time, we use the first-order integrated rate law formula:

\[ [SO_3]_t = [SO_3]_0 e^{-kt} \]

where:
- \([SO_3]_t\) is the concentration of \( SO_3 \) at time \( t \),
- \([SO_3]_0\) is the initial concentration of \( SO_3 \),
- \( k \) is the rate constant (\( 0.0149 \, s^{-1} \)),
- \( t \) is the time (62.0 seconds),
- \( e \) is the base of the natural logarithm.

Now, substitute the given values into the formula.

1. Initial concentration, \( [SO_3]_0 = 1.30 \, M \)
2. Rate constant, \( k = 0.0149 \, s^{-1} \)
3. Time, \( t = 62.0 \, s \)

\[ [SO_3]_t = 1.30 \, M \cdot e^{-(0.0149 \, s^{-1})(62.0 \, s)} \]

Using a calculator to compute the exponent:

\[ [SO_3]_t = 1.30 \, M \cdot e^{-0.9238} \]
\[ [SO_3]_t \approx 1.30 \, M \cdot 0.3966 \]
\[ [SO_3]_t \approx 0.5156 \, M \]

Rounding to 2 significant digits:

\[ [SO_3]_
Transcribed Image Text:### Reaction Rate and Concentration Calculation Consider the following reaction: \[ 2SO_3 (g) \rightarrow 2SO_2 (g) + O_2 (g) \] At a certain temperature, this reaction follows the rate law given by: \[ \text{rate} = (0.0149 \, s^{-1})[SO_3] \] #### Problem Statement Suppose a vessel contains \( SO_3 \) at a concentration of \( 1.30 \, M \). Calculate the concentration of \( SO_3 \) in the vessel after 62.0 seconds. You may assume no other reaction is important. Round your answer to 2 significant digits. #### Solution To calculate the concentration of \( SO_3 \) after a given time, we use the first-order integrated rate law formula: \[ [SO_3]_t = [SO_3]_0 e^{-kt} \] where: - \([SO_3]_t\) is the concentration of \( SO_3 \) at time \( t \), - \([SO_3]_0\) is the initial concentration of \( SO_3 \), - \( k \) is the rate constant (\( 0.0149 \, s^{-1} \)), - \( t \) is the time (62.0 seconds), - \( e \) is the base of the natural logarithm. Now, substitute the given values into the formula. 1. Initial concentration, \( [SO_3]_0 = 1.30 \, M \) 2. Rate constant, \( k = 0.0149 \, s^{-1} \) 3. Time, \( t = 62.0 \, s \) \[ [SO_3]_t = 1.30 \, M \cdot e^{-(0.0149 \, s^{-1})(62.0 \, s)} \] Using a calculator to compute the exponent: \[ [SO_3]_t = 1.30 \, M \cdot e^{-0.9238} \] \[ [SO_3]_t \approx 1.30 \, M \cdot 0.3966 \] \[ [SO_3]_t \approx 0.5156 \, M \] Rounding to 2 significant digits: \[ [SO_3]_
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Rate Laws
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY