Answered: Consider the reaction P4(g) + Cl2(g) →…

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter12: Chemical Equilibrium

Section: Chapter Questions

Problem 12.35PAE: In the reaction in Exercise 12.33, another trial was carried out. The reaction began with an initial...

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1. Consider the reaction P4(g) + Cl2(g) → PCl3(g) Calculate Rate of disappearance of Cl2 Rate of disappearance of PCl3 2. Reaction 1: X + MnO4^- → Mn^2+ + products Reaction 2: Y + MnO4^- → Mn^2+ + products MnO4^- is purple and the products are colorless At the same temperature and instant, Intensity of purple color in 1 > Intensity of purple color in 2 Calculate: Ea of reaction 1 Ea of reaction 2 3. For the reaction: A+B-›P Rate = k[A][B]^2 At the same temperature Calculate: k if [A]0 = 0.10 M and [B]0 = 0.20 M k if [A]0 = 0.20 M and [B]0 = 0.10 M 4. Consider the composition of HI in two containers: HI(g) -» ½ H2(g)+ ½ 12(g) At 25°C, k = 0.020 M min^-1 [HI]0 in container 1 > [HI] o in container 2 Calculate: t 1/2 of reaction in container 1 t 1/2 of reaction in container 2 5. Consider two first-order reactions: Reaction I: G+C-›L Reaction Il: R+J-›M Ea of reaction 1 > Ea of reaction 2 At the same temperature Calculate: t 1/2 of reaction 1 t 1/2 of reaction 2

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