Consider the reaction between acetone and hydrogen cyanide to produce acetone cyanohydrin: a) In this reaction, what types of bonds break (b) what types of bonds form?  (a) Bonds Broken                                          (b) Bonds Formed C-O sigma C-O pi C-C C-O sigma C-O pi C-C C-H O-H no bonds break C-H O-H no bonds form c) If 2.5 g of acetone and 1.0 g of hydrogen cyanide react, how many moles of acetone cyanohydrin (ACH) should form?  d) What was the limiting reagent in part (c)?

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter23: Carbon: Not Just Another Element
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Consider the reaction between acetone and hydrogen cyanide to produce acetone cyanohydrin:

a) In this reaction, what types of bonds break

(b) what types of bonds form? 

(a) Bonds Broken                                          (b) Bonds Formed

C-O sigma C-O pi C-C C-O sigma C-O pi C-C
C-H O-H no bonds break C-H O-H no bonds form


c) If 2.5 g of acetone and 1.0 g of hydrogen cyanide react, how many moles of acetone
cyanohydrin (ACH) should form? 
d) What was the limiting reagent in part (c)?  

The provided image shows a chemical reaction between two molecules, resulting in a product molecule. The left side features the reactants, while the right side depicts the product.

### Reactants:
1. **First Reactant:**
   - Structure: A molecule comprising three carbon (C) atoms in a linear arrangement.
   - Substituents: 
     - The first and second carbons each have three hydrogen (H) atoms attached.
     - The second carbon is double-bonded to an oxygen (O) atom, with the oxygen atom having two lone pairs of electrons.
     - The third carbon is also bonded to three hydrogen atoms.

2. **Second Reactant:**
   - Structure: A molecule consisting of one carbon atom triple-bonded to a nitrogen (N) atom.
   - Substituents:
     - One hydrogen (H) atom attached to the carbon.
     - The nitrogen atom also has a lone pair of electrons.

### Product:
- Structure: A molecule where the combination of the two reactant molecules rearranges into a new structure.
- Substituents:
  - The structure includes three carbon (C) atoms in sequence.
  - The first and second carbon atoms are each bonded to three hydrogens (H).
  - The second carbon maintains a bond with an oxygen (O) atom that has two lone pairs of electrons.
  - The third carbon is single-bonded to two hydrogens and the remaining bonding involves a double bond with nitrogen (N).

### Reaction Summary:
1. The two reactant molecules combine through a process where the bonds rearrange to form a product molecule, maintaining some of the original bonding but creating new structures, particularly the carbon and nitrogen interactions.
2. The double-bonded oxygen (O) remains attached to the second carbon in the product while the triple bond between carbon and nitrogen from the second reactant is now a part of the product structure.

This reaction showcases the principles of organic chemistry, particularly involving carbon, hydrogen, oxygen, and nitrogen atoms and the rearrangement of their bonding configurations to result in different molecular structures.
Transcribed Image Text:The provided image shows a chemical reaction between two molecules, resulting in a product molecule. The left side features the reactants, while the right side depicts the product. ### Reactants: 1. **First Reactant:** - Structure: A molecule comprising three carbon (C) atoms in a linear arrangement. - Substituents: - The first and second carbons each have three hydrogen (H) atoms attached. - The second carbon is double-bonded to an oxygen (O) atom, with the oxygen atom having two lone pairs of electrons. - The third carbon is also bonded to three hydrogen atoms. 2. **Second Reactant:** - Structure: A molecule consisting of one carbon atom triple-bonded to a nitrogen (N) atom. - Substituents: - One hydrogen (H) atom attached to the carbon. - The nitrogen atom also has a lone pair of electrons. ### Product: - Structure: A molecule where the combination of the two reactant molecules rearranges into a new structure. - Substituents: - The structure includes three carbon (C) atoms in sequence. - The first and second carbon atoms are each bonded to three hydrogens (H). - The second carbon maintains a bond with an oxygen (O) atom that has two lone pairs of electrons. - The third carbon is single-bonded to two hydrogens and the remaining bonding involves a double bond with nitrogen (N). ### Reaction Summary: 1. The two reactant molecules combine through a process where the bonds rearrange to form a product molecule, maintaining some of the original bonding but creating new structures, particularly the carbon and nitrogen interactions. 2. The double-bonded oxygen (O) remains attached to the second carbon in the product while the triple bond between carbon and nitrogen from the second reactant is now a part of the product structure. This reaction showcases the principles of organic chemistry, particularly involving carbon, hydrogen, oxygen, and nitrogen atoms and the rearrangement of their bonding configurations to result in different molecular structures.
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