Consider the pair of reactions. Draw the major organic product of each reaction, then predict the type of elimination mechanism,and compare the rates.Reaction 1:wwwHReaction 2::CI::CI:HO-CH3+ HỘ—CH,Draw product 1.Select Draw Templates More/ || ||| C Hmethanol.heatmethanolheatEraseproduct 1product 2Draw product 2.Select Draw Templates More/||||||HErase Identify the mechanism of each reaction.Reaction 2 occurs by an E2 mechanism.Reaction 1 occurs by an E2 mechanism.Reaction 2 occurs by an El mechanism.Reaction 1 occurs by an El mechanism.Compare the rates of each reaction.Reaction 1 is faster than reaction 2.Both reactions occur at the same rate.Reaction 2 is faster than reaction 1.

The question is based on the concept of organic reactions.We need to identify the product formed and explain their mechanism.In 1st case, reactant is tertiary chloride.2nd case : secondary halideSince it is mentioned that we have to consider elimination reaction only, so we consider it. As methanol is not base. They are acidic in nature. So, we can say they are very weak base.In this case, the reaction follow E1 mechanism.In first step , loss of chloride as leaving group takes place to form tertiary carbocation.Now the very weak base methanol abstracts proton to form alkene product.both undergo same E1- elimination mechanism.Since E1 elimination reaction involves formation of carbocation, so rate depends on stability of carbocation; that is first step. In reactant 1; tertiary carbocation is formed which is more stable while second compound forms secondary carbocation which is comparatively less stable.So, first reaction undergoes faster rate. Mechanism;Reaction 1 occurs by E1 mechanismReaction 2 occurs by E1 mechanism Rate;Reaction 1 faster than reaction 2

Science

Chemistry

Consider the pair of reactions. Draw the major organic product of each reaction, then predict the type of elimination mechanism, and compare the rates. Reaction 1: Ma H Reaction 2: :CI: :CI: HO-CH3 + HỘ—CH, Draw product 1. Select Draw Templates More / |||||| C H methanol. heat methanol heat Erase product 1 product 2 Draw product 2. Select Draw Templates More / |||||| H Erase

Consider the pair of reactions. Draw the major organic product of each reaction, then predict the type of elimination mechanism, and compare the rates. Reaction 1: Ma H Reaction 2: :CI: :CI: HO-CH3 + HỘ—CH, Draw product 1. Select Draw Templates More / |||||| C H methanol. heat methanol heat Erase product 1 product 2 Draw product 2. Select Draw Templates More / |||||| H Erase

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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