Consider the following galvanic cell:     E° (V) Sn4+  +  2 e−   →   Sn2+ 0.139 Ag+  +  e−   →   Ag(s) 0.799 What is the cell potential of the galvanic cell if the concentration of Ag(I) is 0.023 M, Sn(II) is 0.34 M, and Sn(IV) is 0.093 M?

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Consider the following galvanic cell:

 

 

E° (V)

Sn4+  +  2 e   →   Sn2+

0.139

Ag+  +  e   →   Ag(s)

0.799

What is the cell potential of the galvanic cell if the concentration of Ag(I) is 0.023 M, Sn(II) is 0.34 M, and Sn(IV) is 0.093 M?

The diagram illustrates a galvanic cell setup commonly used in electrochemistry to demonstrate redox reactions and the flow of electric current. Here’s a detailed explanation of the components:

1. **Electrodes:**
   - **Sn Electrode (Tin):** On the left side, there is a tin electrode immersed in a solution containing tin ions (Sn²⁺, Sn⁴⁺).
   - **Ag Electrode (Silver):** On the right side, a silver electrode is immersed in a solution containing silver ions (Ag⁺).

2. **Salt Bridge:**
   - The salt bridge, labeled KCl, connects the two solutions. It is usually a U-shaped tube filled with a salt solution (potassium chloride in this case) that allows the flow of ions to maintain electrical neutrality in both compartments.

3. **Circuit:**
   - A wire connects the electrodes, allowing electrons to flow from the tin electrode to the silver electrode. This external circuit also includes a device, possibly a voltmeter or a load, that measures or utilizes the flow of electrons.

**Function:**
- In this cell, the tin electrode undergoes oxidation, losing electrons, while the silver ions gain electrons and reduce at the silver electrode. This transfer of electrons generates an electric current, which can be harnessed to do work.

This setup is an example of a galvanic cell where a spontaneous redox reaction occurs, converting chemical energy into electrical energy.
Transcribed Image Text:The diagram illustrates a galvanic cell setup commonly used in electrochemistry to demonstrate redox reactions and the flow of electric current. Here’s a detailed explanation of the components: 1. **Electrodes:** - **Sn Electrode (Tin):** On the left side, there is a tin electrode immersed in a solution containing tin ions (Sn²⁺, Sn⁴⁺). - **Ag Electrode (Silver):** On the right side, a silver electrode is immersed in a solution containing silver ions (Ag⁺). 2. **Salt Bridge:** - The salt bridge, labeled KCl, connects the two solutions. It is usually a U-shaped tube filled with a salt solution (potassium chloride in this case) that allows the flow of ions to maintain electrical neutrality in both compartments. 3. **Circuit:** - A wire connects the electrodes, allowing electrons to flow from the tin electrode to the silver electrode. This external circuit also includes a device, possibly a voltmeter or a load, that measures or utilizes the flow of electrons. **Function:** - In this cell, the tin electrode undergoes oxidation, losing electrons, while the silver ions gain electrons and reduce at the silver electrode. This transfer of electrons generates an electric current, which can be harnessed to do work. This setup is an example of a galvanic cell where a spontaneous redox reaction occurs, converting chemical energy into electrical energy.
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