Consider the following equilibrium: 2NO₂ (g) N₂O₂(g) AG=-5.4 kJ Now suppose a reaction vessel is filled with 6.98 atm of dinitrogen tetroxide (N₂O) at 1001. °C. Answer the following questions about this system: Under these conditions, will the pressure of N₂O tend to rise or fall? Is it possible to reverse this tendency by adding NO₂? In other words, if you said the pressure of N₂O₂ will tend to rise, can that be changed to a tendency to fall by adding NO₂? Similarly, if you said the pressure of N₂O will tend to fall, can that be changed to a tendency to rise by adding NO₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO, needed to reverse it. Round your answer to 2 significant digits. rise O fall O yes O no X

Chemistry
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**Using Reaction Free Energy to Predict Equilibrium Composition**

**Consider the following equilibrium:**

\[ 2NO_2(g) \leftrightarrow N_2O_4(g) \quad \Delta G^\circ = -5.4 \, \text{kJ} \]

Now suppose a reaction vessel is filled with 6.98 atm of dinitrogen tetroxide (\( N_2O_4 \)) at 1001 °C. Answer the following questions about this system:

1. **Under these conditions, will the pressure of \( N_2O_4 \) tend to rise or fall?**
   - Options: Rise / Fall

2. **Is it possible to reverse this tendency by adding \( NO_2 \)?**
   - In other words, if you said the pressure of \( N_2O_4 \) will tend to rise, can that be changed to a tendency to fall by adding \( NO_2 \)? Similarly, if you said the pressure of \( N_2O_4 \) will tend to fall, can that be changed to a tendency to rise by adding \( NO_2 \)?
   - Options: Yes / No

3. **Assuming the tendency can be reversed in the second question, calculate the minimum pressure of \( NO_2 \) needed to reverse it.**
   - Enter answer in \( \text{atm} \).

**Note:** Round your answer to 2 significant digits.

(Interactive elements: Explanation button and Check button for answers)
Transcribed Image Text:**Using Reaction Free Energy to Predict Equilibrium Composition** **Consider the following equilibrium:** \[ 2NO_2(g) \leftrightarrow N_2O_4(g) \quad \Delta G^\circ = -5.4 \, \text{kJ} \] Now suppose a reaction vessel is filled with 6.98 atm of dinitrogen tetroxide (\( N_2O_4 \)) at 1001 °C. Answer the following questions about this system: 1. **Under these conditions, will the pressure of \( N_2O_4 \) tend to rise or fall?** - Options: Rise / Fall 2. **Is it possible to reverse this tendency by adding \( NO_2 \)?** - In other words, if you said the pressure of \( N_2O_4 \) will tend to rise, can that be changed to a tendency to fall by adding \( NO_2 \)? Similarly, if you said the pressure of \( N_2O_4 \) will tend to fall, can that be changed to a tendency to rise by adding \( NO_2 \)? - Options: Yes / No 3. **Assuming the tendency can be reversed in the second question, calculate the minimum pressure of \( NO_2 \) needed to reverse it.** - Enter answer in \( \text{atm} \). **Note:** Round your answer to 2 significant digits. (Interactive elements: Explanation button and Check button for answers)
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