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- Recall for an the hydrogenic (single electron) atom 2s (r) = 2,0,0 (r, 0, 4) Φ2p (r) = Φ2,1,0 (r,θ, φ) - = 2p (7) = 2p_ (F) = 2,1,1 (r, 0, 6): = 2,1,-1 (r, 0,6) 1 4√2π/² p 1 3/2 ao 4√/2πа = 2 δεν παρ Tº 3/2 ao 8√πа 3/2 ao 1) e-r/2² ao e ○ (02s (71)2p, (72) + O2p. (71)02s (72)) O 02s (1) 2po (2) ○(28 (71)2p, (72) – $2p. (71)¢2s (72)) O 02s (1)02s (F2) T -T 12a0 •/200 cos 0, /2ao sin 0 etic. r/2ao sin 0 e-iç Consider the helium atom (two electron system). Suppose the spin part is one of the triplet. Which of the following can be a possible space part?A spin-particle is in the spin state |A), described by the ket 7 i |4) = 5√2 tu) +5√2 tu). (a) Verify that A) is normalised. (b) Using the spinor representation (+₂) = ₁ | +) = √/2₁ 11³) = ₁ 1 +2) = [8] find the values of c₁ and c₂ for which |A) = C₁|1₂) + C₂l+₂). (c) If the observable S₂ is measured in the spin state |A), what values can be obtained and what are their probabilities? (d) Find the expectation value of S₂ in the spin state [A). (e) With reference to the properties of angular momentum, explain briefly how the results of the Stern-Gerlach experiment provide evidence of the existence of spin.Calculate the number of angles that L can make with the z-axis for an l=3 electron.
- (d) The following orbital belongs to the 3d subshell of the Hydrogen atom: r Y(r, 0, 0) = A(Z) θ, φ) 2 r e 3ao sin² (0) e²i зао where A and ao are constants. Using the operator for the z-component of orbital angular momentum (L₂ = -ih d/do) determine the m, for this particular orbital. (e) Consider the wavefunction, r r Y(r,0,0) = A-e 2do cos(0) do (i) Identify the radial part of this orbital function and the number of radial nodes. (ii) Identify the angular part of the orbital function and the number of angular nodes. Z (iii) Using this information and the L₂ = -ih d/do operator obtain the n, 1, and, m quantum numbers and identify the orbital.Rewrite S₁ S₂ in terms of S², |S₁|², 5₂|² by using the identity |S² = |S₁ + S₂|² = |S₁|² + |5₂|² +25₁ · 5₂. Use this to show that the combined spin angular momentum basis 5² for the electron and proton spins is an eigenstate basis for this dipole interaction.We have a three dimensional vector space where |P1), |P2) and |23) form a complete orthonormal basis. In this vector space we have two states |a)=5i|1)+3i 2)+(-2+2i) 3) and |B) =4i|1)-5 i) Calculate (a and (B, in terms of the dual basis vectors (y|, (p2|, (P3|. ii) Calculate the inner/scalar products (alB) and (Ba). Show that (8|a) =(a|B)".