A particle rotating on the surface of a sphere with fixed r has the quantum numbers | = 2 and m = 1. What is the value of the z-component of the angular momentum? On 2h 6n2
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- Consider the atom having the electron configuration 1s2 2s2 2p6 3s2. Assume that the z components of both the orbital abd spin angular momenta of the electron in the 3p subshell are positive. What are the quantum numbers that describe the state of this electron. n=3 l=1 m=-1 s=1/2n=3 l=1 m=2 s=1/2n=3 l=2 m=1 s=1/2n=3 l=1 m=1 s=1/2n=3 l=2 m=2 s=-1/2 Can we say which one is correct?Calculate the number of angles that L can make with the z-axis for an l=3 electron.If we neglect interaction between electrons, the ground state energy of the helium atom is E =2 z2((- e2)/(2ao)) = -108.848eV (Z=2). The true (measured) value is – 79.006eV.Calculate the interaction energy e2/r12 supposing that both electrons are in the 1s state and r12 that the spin wave function is anti-symmetric. What E is the ground state energy?
- Q.10 A. Show that the maximum angular quantum number of a diatomic rigid rotor is given by Jmax KT 2hcB 1 12For a ground state Cd atom (Z = 48), how many electrons in total have an angular quantum number ℓ = 0 ?(a) How many angles can L make with the z -axis for an l = 2 electron? (b) Calculate the value of the smallest angle.
- Answer the following. (a) Write out the electronic configuration of the ground state for nitrogen (Z = 7). 1s22s22p11s22s22p2 1s22s22p31s22s22p41s22s22p51s22s22p6 (b) Write out the values for the set of quantum numbers n, ℓ, m, and ms for each of the electrons in nitrogen. (In cases where there are more than one value, enter the positive value first. Enter positive values without a '+' sign in front of them. Include all possible values.) 1s states n = ℓ = m = ms = ms = 2s states n = ℓ = m = ms = ms = 2p states n = ℓ = m = ms = ms = m = ms = ms = m = ms = ms =Consider a two-electron spin system in a singlet state. a. If a measurement of one of the electrons shows that it is in a state with sz = 1/2, what is the probability of obtaining another state with sz= +1/2? b. If a measurement of one of the electrons shows that it is in a state with sx = 1/2, what is the probability of obtaining another state with sy = +1/2?In a particular state of the hydrogen atom, the angle between the angular momentum vector L →and the z-axis is u = 26.6°. If this is the smallest angle for this particular value of the orbital quantum number l, what is l?