Consider a cell undergoing the reaction below at 298 K 2 Na (s) + Cd²+(aq) <=> 2 Na+ (aq) + Cd (s) When [Na] 0.0005 molal (y=0.974) and [Cd²+] = 0.2 molal (y 0.102), then Ecell =+2.45 V. What is Eº for the cell =
Consider a cell undergoing the reaction below at 298 K 2 Na (s) + Cd²+(aq) <=> 2 Na+ (aq) + Cd (s) When [Na] 0.0005 molal (y=0.974) and [Cd²+] = 0.2 molal (y 0.102), then Ecell =+2.45 V. What is Eº for the cell =
Chemistry
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Chapter1: Chemical Foundations
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![**Electrochemical Cell Analysis at 298 K**
Consider a cell undergoing the reaction below at 298 K:
\[ 2 \text{Na (s)} + \text{Cd}^{2+} \text{(aq)} \leftrightarrows 2 \text{Na}^{+} \text{(aq)} + \text{Cd (s)} \]
When \([ \text{Na}^{+} ] = 0.0005 \text{ molal} \, (\gamma = 0.974)\) and \([ \text{Cd}^{2+} ] = 0.2 \text{ molal} \, (\gamma = 0.102)\), then \(\text{E}_{\text{cell}} = +2.45 \text{ V}\). What is \(\text{E}^\circ\) for the cell?
**Explanation**
- "Na" represents sodium, which in its solid form is a reactant.
- "Cd" is cadmium, with its ions present in aqueous solution in this reaction.
- \(\gamma\) represents the activity coefficient for each ion concentration.
- \(\text{E}_{\text{cell}}\) denotes the electromotive force (EMF) under the given conditions.
- The goal is to find \(\text{E}^\circ\), the standard cell potential.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F806b78c5-9900-4411-98f9-2789e3c4ff7a%2F819cfc4c-e6e2-4211-9ab2-ce905feca11a%2Fv2wjja_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Electrochemical Cell Analysis at 298 K**
Consider a cell undergoing the reaction below at 298 K:
\[ 2 \text{Na (s)} + \text{Cd}^{2+} \text{(aq)} \leftrightarrows 2 \text{Na}^{+} \text{(aq)} + \text{Cd (s)} \]
When \([ \text{Na}^{+} ] = 0.0005 \text{ molal} \, (\gamma = 0.974)\) and \([ \text{Cd}^{2+} ] = 0.2 \text{ molal} \, (\gamma = 0.102)\), then \(\text{E}_{\text{cell}} = +2.45 \text{ V}\). What is \(\text{E}^\circ\) for the cell?
**Explanation**
- "Na" represents sodium, which in its solid form is a reactant.
- "Cd" is cadmium, with its ions present in aqueous solution in this reaction.
- \(\gamma\) represents the activity coefficient for each ion concentration.
- \(\text{E}_{\text{cell}}\) denotes the electromotive force (EMF) under the given conditions.
- The goal is to find \(\text{E}^\circ\), the standard cell potential.
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