Consider a buffer made by adding 42.3 g of (CH3)2NH2I to 250.0 mL of 1.42 M (CH:)»NH (Kb = 5.4 x 10 4) What is the pH of the buffer after 0.300 mol of Ht have been added?

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**Buffer Preparation and pH Calculation**

**Scenario:**
Consider a buffer made by adding 42.3 g of (CH₃)₂NH₂I to 250.0 mL of 1.42 M (CH₃)₂NH.

**Given:**
- The base dissociation constant (Kb) for (CH₃)₂NH is 5.4 x 10⁻⁴.

**Question:**
What is the pH of the buffer after 0.300 mol of H⁺ have been added?

**Steps for Calculation:**

1. **Determine the Moles of Each Component:**
   - Calculate moles of (CH₃)₂NH₂I using its molar mass.
   - Calculate initial moles of (CH₃)₂NH using its concentration and volume.

2. **Buffer Reaction:**
   - Consider the buffer reaction between (CH₃)₂NH and added H⁺ ions.
   - Adjust the moles of components based on the reaction with H⁺.

3. **Utilize the Henderson-Hasselbalch Equation:**
   - Use the pKb to find the pKa.
   - Apply the equation to find the pH of the buffer solution after the addition of H⁺ ions.  

This problem involves using concepts of buffer solution chemistry and equilibrium constants to calculate the resulting pH when an acid is introduced to the system.
Transcribed Image Text:**Buffer Preparation and pH Calculation** **Scenario:** Consider a buffer made by adding 42.3 g of (CH₃)₂NH₂I to 250.0 mL of 1.42 M (CH₃)₂NH. **Given:** - The base dissociation constant (Kb) for (CH₃)₂NH is 5.4 x 10⁻⁴. **Question:** What is the pH of the buffer after 0.300 mol of H⁺ have been added? **Steps for Calculation:** 1. **Determine the Moles of Each Component:** - Calculate moles of (CH₃)₂NH₂I using its molar mass. - Calculate initial moles of (CH₃)₂NH using its concentration and volume. 2. **Buffer Reaction:** - Consider the buffer reaction between (CH₃)₂NH and added H⁺ ions. - Adjust the moles of components based on the reaction with H⁺. 3. **Utilize the Henderson-Hasselbalch Equation:** - Use the pKb to find the pKa. - Apply the equation to find the pH of the buffer solution after the addition of H⁺ ions. This problem involves using concepts of buffer solution chemistry and equilibrium constants to calculate the resulting pH when an acid is introduced to the system.
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