Complete the Lewis structures for COCI2 and SOCI2 using the skeletal structure shown below, being sure to follow the procedure for minimizing the sum of the absolute values for the formal charges, where the octet rule need not be followed. Based on the complete structures, which statement below is true? [aid Hint: Consider the potential for multiple bonds on the molecules and be sure to account for all valence electrons. O The NOCI₂* exhibits both residual formal charges and resonance hybrids, while the BrOCI₂ exhibits formal charges but no resonance hybrids. O No answer text provided. The NOC₂ exhibits both formal charges and resonance hybrids, while the BrOCI₂ exhibits resonance hybrids but no formal charges. O At least one atom in each molecule exhibits formal charges, and the molecules have no resonance hybrids. O The BrOCl₂ exhibits both formal charges and resonance hybrids, while the POCI₂* exhibits resonance hybrids but no formal charges. O The NOC₂ exhibits formal charges but no resonance hybrids, while the BrOCI₂* exhibits both formal charges and resonance hybrids. O The BrOCl₂ exhibits formal charges but no resonance hybrids, while the NOCI₂* exhibits resonance hybrids but no formal charges.

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**Title: Understanding Lewis Structures: COCl₂ and SOCl₂**

**Objective:**

Complete the Lewis structures for COCl₂ and SOCl₂ using the provided skeletal structures. Follow the procedure to minimize the sum of the absolute values for the formal charges, where the octet rule need not be strictly followed. Determine which statement is true based on the complete structures.

**Molecular Structures:**

1. \[ \text{Cl} - \overset{+}{\text{N}} = \overset{-}{\text{O}} - \text{Cl} \]
2. \[ \text{Cl} - \overset{+}{\text{Br}} = \overset{-}{\text{O}} - \text{Cl} \]

**Hint:**

Consider the potential for multiple bonds on the molecules and account for all valence electrons.

**Statements to Evaluate:**

- The NOCl₂⁺ exhibits both residual formal charges and resonance hybrids, while the BrOCl₂⁺ exhibits formal charges but no resonance hybrids.
- No answer text provided.
- The NOCl₂⁺ exhibits both formal charges and resonance hybrids, while the BrOCl₂⁺ exhibits resonance hybrids but no formal charges. *(Correct Answer)*
- At least one atom in each molecule exhibits formal charges, and the molecules have no resonance hybrids.
- The BrOCl₂⁺ exhibits both formal charges and resonance hybrids, while the POCl₂⁺ exhibits resonance hybrids but no formal charges.
- The NOCl₂⁺ exhibits formal charges but no resonance hybrids, while the BrOCl₂⁺ exhibits both formal charges and resonance hybrids.
- The BrOCl₂⁺ exhibits formal charges but no resonance hybrids, while the NOCl₂⁺ exhibits resonance hybrids but no formal charges.

**Discussion:**

In determining the correct answer, it is essential to analyze the provided structures for the presence of formal charges and possible resonance hybrids. The correct statement highlighted indicates that the NOCl₂⁺ structure exhibits both formal charges and resonates, whereas the BrOCl₂⁺ only resonates without formal charges. This distinction is crucial for understanding molecular stability and behavior.
Transcribed Image Text:**Title: Understanding Lewis Structures: COCl₂ and SOCl₂** **Objective:** Complete the Lewis structures for COCl₂ and SOCl₂ using the provided skeletal structures. Follow the procedure to minimize the sum of the absolute values for the formal charges, where the octet rule need not be strictly followed. Determine which statement is true based on the complete structures. **Molecular Structures:** 1. \[ \text{Cl} - \overset{+}{\text{N}} = \overset{-}{\text{O}} - \text{Cl} \] 2. \[ \text{Cl} - \overset{+}{\text{Br}} = \overset{-}{\text{O}} - \text{Cl} \] **Hint:** Consider the potential for multiple bonds on the molecules and account for all valence electrons. **Statements to Evaluate:** - The NOCl₂⁺ exhibits both residual formal charges and resonance hybrids, while the BrOCl₂⁺ exhibits formal charges but no resonance hybrids. - No answer text provided. - The NOCl₂⁺ exhibits both formal charges and resonance hybrids, while the BrOCl₂⁺ exhibits resonance hybrids but no formal charges. *(Correct Answer)* - At least one atom in each molecule exhibits formal charges, and the molecules have no resonance hybrids. - The BrOCl₂⁺ exhibits both formal charges and resonance hybrids, while the POCl₂⁺ exhibits resonance hybrids but no formal charges. - The NOCl₂⁺ exhibits formal charges but no resonance hybrids, while the BrOCl₂⁺ exhibits both formal charges and resonance hybrids. - The BrOCl₂⁺ exhibits formal charges but no resonance hybrids, while the NOCl₂⁺ exhibits resonance hybrids but no formal charges. **Discussion:** In determining the correct answer, it is essential to analyze the provided structures for the presence of formal charges and possible resonance hybrids. The correct statement highlighted indicates that the NOCl₂⁺ structure exhibits both formal charges and resonates, whereas the BrOCl₂⁺ only resonates without formal charges. This distinction is crucial for understanding molecular stability and behavior.
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