Co2 (g) H20 (1) CH1206(s) 01e) this pro T = 298 K AH /kJ mol -393.5 -285.8 213.8 -1273.1 0.0 70.0 209.2 2052 S/J mol K CP.m/J mol K-I 37.1 75.3 219.2 294 Calculate the entropy and enthalpy changes for this chemical system at T = 298.15 K and T = 365 K. Also calculate the entropy change of the surroundings and the universe at both temperatures. %3D

Chemistry
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Chapter1: Chemical Foundations
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**Photosynthesis Reaction and Thermodynamic Data**

**Section 5.9**

**Problem P5.32**

Consider the formation of glucose from carbon dioxide and water, i.e., the photosynthetic process:

\[
6\text{CO}_2(g) + 6\text{H}_2\text{O}(l) \rightarrow \text{C}_6\text{H}_{12}\text{O}_6(s) + 6\text{O}_2(g).
\]

The following table of information will be useful for solving this problem:

**Table: Thermodynamic Data at \(T = 298 \, \text{K}\)**

\[
\begin{array}{|c|c|c|c|c|}
\hline
& \text{CO}_2(g) & \text{H}_2\text{O}(l) & \text{C}_6\text{H}_{12}\text{O}_6(s) & \text{O}_2(g) \\
\hline
\Delta_f H^\circ \, [\text{kJ mol}^{-1}] & -393.5 & -285.8 & -1273.1 & 0.0 \\
\hline
S^\circ \, [\text{J mol}^{-1} \text{K}^{-1}] & 213.8 & 70.0 & 209.2 & 205.2 \\
\hline
C_{P,m} \, [\text{J mol}^{-1} \text{K}^{-1}] & 37.1 & 75.3 & 219.2 & 29.4 \\
\hline
\end{array}
\]

**Task:**

Calculate the entropy and enthalpy changes for the chemical system at \(T = 298.15 \, \text{K}\) and \(T = 365 \, \text{K}\). Additionally, calculate the entropy change of the surroundings and the universe at both temperatures.
Transcribed Image Text:**Photosynthesis Reaction and Thermodynamic Data** **Section 5.9** **Problem P5.32** Consider the formation of glucose from carbon dioxide and water, i.e., the photosynthetic process: \[ 6\text{CO}_2(g) + 6\text{H}_2\text{O}(l) \rightarrow \text{C}_6\text{H}_{12}\text{O}_6(s) + 6\text{O}_2(g). \] The following table of information will be useful for solving this problem: **Table: Thermodynamic Data at \(T = 298 \, \text{K}\)** \[ \begin{array}{|c|c|c|c|c|} \hline & \text{CO}_2(g) & \text{H}_2\text{O}(l) & \text{C}_6\text{H}_{12}\text{O}_6(s) & \text{O}_2(g) \\ \hline \Delta_f H^\circ \, [\text{kJ mol}^{-1}] & -393.5 & -285.8 & -1273.1 & 0.0 \\ \hline S^\circ \, [\text{J mol}^{-1} \text{K}^{-1}] & 213.8 & 70.0 & 209.2 & 205.2 \\ \hline C_{P,m} \, [\text{J mol}^{-1} \text{K}^{-1}] & 37.1 & 75.3 & 219.2 & 29.4 \\ \hline \end{array} \] **Task:** Calculate the entropy and enthalpy changes for the chemical system at \(T = 298.15 \, \text{K}\) and \(T = 365 \, \text{K}\). Additionally, calculate the entropy change of the surroundings and the universe at both temperatures.
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