Using the table of standard thermodynamic quantities, provided below, estimate the boiling point of CHCl3. The boiling point from literature is 61.2⁰C. Compare your calculated result with it and explain why if they are not the same. **Table 2.3.2 – Inorganic Compounds**This table provides a list of various inorganic compounds, presenting their formulas, names, phases, and thermodynamic data, including standard enthalpy of formation \((\Delta H_f^\circ)\) and standard Gibbs free energy of formation \((\Delta G_f^\circ)\) at 298 K.| Formula | Name | Phase | \(\Delta H_f^\circ_{298}\,[\text{kJ/mol}]\) | \(\Delta G_f^\circ_{298}\,[\text{kJ/mol}]\) | |---------|--------------------------|-------|------------------------------|-------------------------------| | BCl₃ | Boron trichloride | G | -402.96 | -387.96 | | B₂H₆ | Diborane | G | 35.61 | 86.77 | | BN | Boron nitride | S | -254.387 | -228.501 | | B₂O₃ | Boron oxide | S | -1271.94 | -1192.8 | | CCl₃F | Trichlorofluoromethane | G | -284.70 | -245.51 | | CF₄ | Carbon tetrafluoride | G | -975.52 | -889.03 | | C₂F₆ | Hexafluoroethane | G | -1343.06 | -1257.3 | | CHCl₃ | Chloroform | L | -132.30 | -71.89 | | CHCl₃ | Chloroform | G | -101.32 | -68.58 | | CHN | Hydrogen cyanide | G | 130.63 | 120.20 | | CO | Carbon monoxide | G | -110.53 | -137.17 | | CO₂ | Carbon dioxide | G | -393.51 | -394.36 | | CS₂ | Carbon disulfide | G

In order to calculate the boiling point, we need data for entropy and not the gibbs free energy, therefore the entropy data is taken from google. Given data, ∆HfoCHCl3(g)=-101.32kj/mol∆HfoCHCl3(l)=-132.30kJ/mol∆SfoCHCl3(g)=295.6J/mol.K (taken from google)∆SfoCHCl3(l)=201.7J/mol.K (taken from google)At boiling point, the liquid and gaseous phase of the substance comes at equilibrium, therefore the change in gibbs free energy becomes zero. Now, we need to calculate the enthalpy and entropy change for the conversion of liquid to gas. CHCl3(l)⇌CHCl3(g)∆Horxn=∆HfoCHCl3(g)-∆HfoCHCl3(l)=-101.32kj/mol-(-132.30)kj/mol=+30.98kj/mol∆Sorxn=∆SfoCHCl3(g)-∆SfoCHCl3(l)=295.6J/mol.K-201.7J/mol.K=93.9J/mol.K=0.0939kJ/mol.K∆Go=∆Ho-T∆So∆Ho-T∆So=0T∆So=∆HoT=∆Ho∆So=30.98kJ/mol0.0939kJ/mol.K=329.92KT=329.925-273.15=56.775oC The literature value of boiling point of CHCl3 is 61.2oC and the estimated value comes out be 56.775oC which is lower than the literature value. The difference in boiling point results from the assumption that we have considered that there is no change in enthalpy and entropy value at boiling point.