„CN and ČN

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The question  is about which compound exhibits 1,3-diaxial interaction by calculating the Steric Strain energy difference (use the attached 1,3-diaxial strain E values )

CN
and
ČN
Transcribed Image Text:CN and ČN
Conformation of Monosubstituted Cyclohexane
Steric Strain in Monosubstituted Cyclohexanes
H+
1,3-Diaxial strain
(kJ/mol)
(kcal/mol)
F
0.5
0.12
CI, Br
1.0
0.25
он
2.1
0.5
CH3
3.8
0.9
CH2CH3
4.0
0.95
CH(CH3)2
4.6
1.1
CICH3)3
11.4
2.7
6.3
1.5
CO,H
2.9
0.7
CN
0.4
0.1
Transcribed Image Text:Conformation of Monosubstituted Cyclohexane Steric Strain in Monosubstituted Cyclohexanes H+ 1,3-Diaxial strain (kJ/mol) (kcal/mol) F 0.5 0.12 CI, Br 1.0 0.25 он 2.1 0.5 CH3 3.8 0.9 CH2CH3 4.0 0.95 CH(CH3)2 4.6 1.1 CICH3)3 11.4 2.7 6.3 1.5 CO,H 2.9 0.7 CN 0.4 0.1
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