• Circle the type(s) of reactions which would have rearrangements occur. SN1 SN2 El E2 • Propose a reason (driving force) for this rearrangement to occur. (Hint: consider stability of the intermediates).

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9. Rearrangements (aka 1,2 shifts)
1,2 Hydride Shifts can occur when a carbocation has formed. The H slides from one atom to
the adjacent atom (shown below).
H,C CH,
H,C
CH,
H,C
CH,
H3C
CH3
H,C
H Br
H
Nú
H
Circle the type(s) of reactions which would have rearrangements occur.
SN1
SN2
El
E2
• Propose a reason (driving force) for this rearrangement to occur. (Hint: consider
stability of the intermediates).
Transcribed Image Text:9. Rearrangements (aka 1,2 shifts) 1,2 Hydride Shifts can occur when a carbocation has formed. The H slides from one atom to the adjacent atom (shown below). H,C CH, H,C CH, H,C CH, H3C CH3 H,C H Br H Nú H Circle the type(s) of reactions which would have rearrangements occur. SN1 SN2 El E2 • Propose a reason (driving force) for this rearrangement to occur. (Hint: consider stability of the intermediates).
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