CH₂OH C=O CH₂OPO DHAP Triose phosphate isomerase H C O HCOH I CH₂OPO G-3-P Under standard conditions, AG° = +7.53 kJ/mol. What is AG when the initial concentration of DHAP is 2 x 10-4 M and the initial concentration of G-3-P is 3 x 10-6 M? R = 8.314 x 10-3 kJ*mol-¹*K-1 T = 310 K
CH₂OH C=O CH₂OPO DHAP Triose phosphate isomerase H C O HCOH I CH₂OPO G-3-P Under standard conditions, AG° = +7.53 kJ/mol. What is AG when the initial concentration of DHAP is 2 x 10-4 M and the initial concentration of G-3-P is 3 x 10-6 M? R = 8.314 x 10-3 kJ*mol-¹*K-1 T = 310 K
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Reaction Overview
The image illustrates the isomerization reaction between Dihydroxyacetone phosphate (DHAP) and Glyceraldehyde 3-phosphate (G-3-P) catalyzed by the enzyme triose phosphate isomerase.
**Chemical Structures:**
- **DHAP (Dihydroxyacetone phosphate):**
- Structural Formula:
- \( \text{CH}_2\text{OH} \)
- \( | \)
- \( \text{C} \)
- \( || \)
- \( \text{O} \)
- \( | \)
- \( \text{CH}_2\text{OPO}_3^{2-} \)
- **G-3-P (Glyceraldehyde 3-phosphate):**
- Structural Formula:
- \( \text{H} \)
- \( | \)
- \( \text{C} \)
- \( || \)
- \( \text{O} \)
- \( | \)
- \( \text{HCOH} \)
- \( | \)
- \( \text{CH}_2\text{OPO}_3^{2-} \)
### Reaction Conditions
Under standard conditions:
- \(\Delta G^\circ = +7.53 \text{ kJ/mol}\)
To find \(\Delta G\) under specific conditions:
- **Initial Concentration of DHAP:** \(2 \times 10^{-4} \text{ M}\)
- **Initial Concentration of G-3-P:** \(3 \times 10^{-6} \text{ M}\)
### Constants
- **R (Universal Gas Constant):** \(8.314 \times 10^{-3} \text{ kJ} \cdot \text{mol}^{-1} \cdot \text{K}^{-1}\)
- **T (Temperature):** \(310 \text{ K}\)
This setup is used to calculate the Gibbs free energy (\(\Delta G\)) for the reaction based on the provided concentrations and conditions using the equation:
\[
\Delta G = \Delta G^\circ + RT \ln \left(\frac{[\text{G-3-P}]}{[\text{DHAP}]}\right)
\]
This equation allows for determining the energy change](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F54a9d33b-c075-4af5-8013-3f49004b10ba%2Fd890279d-390c-43cc-b9c6-9b910dc6c239%2Ff0p0z66_processed.png&w=3840&q=75)
Transcribed Image Text:### Reaction Overview
The image illustrates the isomerization reaction between Dihydroxyacetone phosphate (DHAP) and Glyceraldehyde 3-phosphate (G-3-P) catalyzed by the enzyme triose phosphate isomerase.
**Chemical Structures:**
- **DHAP (Dihydroxyacetone phosphate):**
- Structural Formula:
- \( \text{CH}_2\text{OH} \)
- \( | \)
- \( \text{C} \)
- \( || \)
- \( \text{O} \)
- \( | \)
- \( \text{CH}_2\text{OPO}_3^{2-} \)
- **G-3-P (Glyceraldehyde 3-phosphate):**
- Structural Formula:
- \( \text{H} \)
- \( | \)
- \( \text{C} \)
- \( || \)
- \( \text{O} \)
- \( | \)
- \( \text{HCOH} \)
- \( | \)
- \( \text{CH}_2\text{OPO}_3^{2-} \)
### Reaction Conditions
Under standard conditions:
- \(\Delta G^\circ = +7.53 \text{ kJ/mol}\)
To find \(\Delta G\) under specific conditions:
- **Initial Concentration of DHAP:** \(2 \times 10^{-4} \text{ M}\)
- **Initial Concentration of G-3-P:** \(3 \times 10^{-6} \text{ M}\)
### Constants
- **R (Universal Gas Constant):** \(8.314 \times 10^{-3} \text{ kJ} \cdot \text{mol}^{-1} \cdot \text{K}^{-1}\)
- **T (Temperature):** \(310 \text{ K}\)
This setup is used to calculate the Gibbs free energy (\(\Delta G\)) for the reaction based on the provided concentrations and conditions using the equation:
\[
\Delta G = \Delta G^\circ + RT \ln \left(\frac{[\text{G-3-P}]}{[\text{DHAP}]}\right)
\]
This equation allows for determining the energy change
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