Chlorine dioxide (CIO,) is a disinfectant used to treat municipal wastewater. When dissolved in alkaline solution, CIO3 and ClO2 are produced as shown in the reaction below. 2C10, (aq) + 20H (aq)→ ClO,¯ (aq) + ClO," (aq) + H,0 (1) 2CIO, (aq) + 20н (ад) —> СІО, (aд) + CIO, (aq) + H,О () Consider the following data that were collected for this reaction. Exp [C10,]Imitr M Initial Rate, M/s Temperature, ºC W "[-HO] 1 0.020 0.050 1.4 X 10-3 25.0 2 0.020 0.100 2.8 X 10-3 25.0 0.010 0.050 7.0 X 10-4 25.0 4 0.020 0.050 6.0 X 10-3 38.0 0.020 0.050 2.3 X 10-2 51.0 Exp [CIO, Imt, M [OH ]Imitr M Initial Rate, M/s Temperature, ºC 1 0.020 0.050 1.4 X 10-3 25.0 2 0.020 0.100 2.8 X 10-3 25.0 3 0.010 0.050 7.0 X 10-4 25.0 4 0.020 0.050 6.0 X 10-3 38.0 5 0.020 0.050 2.3 X 10-2 51.0 Question 1 Determine the reaction order with respect to CIO2 (aq) and он (аq). Exp [C10,]mitr M [OH ]mit, M Initial Rate, M/s Temperature, °C 1 0.020 0.050 1.4 X 10-3 25.0 2 0.020 0.100 2.8 X 10-3 25.0 3 0.010 0.050 7.0 X 10-4 25.0 4 0.020 0.050 6.0 X 10-3 38.0 0.020 0.050 2.3 X 10-2 51.0

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Chapter1: Chemical Foundations
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Chlorine dioxide (CIO2) is a disinfectant used to
treat municipal wastewater. When dissolved in
alkaline solution, CIO3 and ClO,¯ are produced as
shown in the reaction below.
2CIO, (aq) + 20H (aq)→ ClO,¯ (aq) + ClO,¯ (aq) + H,0 (1)
2C10, (aq) + 20H (aq)→ Cl0,¯ (aq) + ClO,¯ (aq) +H,0 (1)
Consider the following data that were collected
for this reaction.
Exp
[10,]nit, M
[OH ]initr M
Initial Rate, M/s
Temperature, °C
1
0.020
0.050
1.4 X 10-3
25.0
2
0.020
0.100
2.8 X 10-3
25.0
3
0.010
0.050
7.0 X 104
25.0
0.020
0.050
6.0 X 10-3
38.0
0.020
0.050
2.3 X 10-2
51.0
Exp
[10, ]mt, M
[OH Imitr M
Initial Rate, M/s
Temperature, ºC
1
0.020
0.050
1.4 X 10-3
25.0
0.020
0.100
2.8 X 10-3
25.0
0.010
0.050
7.0 X 10-4
25.0
4
0.020
0.050
6.0X 10-3
38.0
0.020
0.050
2.3 X 10-2
51.0
Question 1
Determine the reaction order with respect to
ClO, (aq) and OH- (aq).
Exp
[C0,]mitr M
[OH ]mit, M
Initial Rate, M/s
Temperature, ºc
1
0.020
0.050
1.4 X 10-3
25.0
0.020
0.100
2.8 X 10-3
25.0
0.010
0.050
7.0 X 10-4
25.0
4
0.020
0.050
6.0 X 10-3
38.0
5
0.020
0.050
2.3 X 10-2
51.0
Transcribed Image Text:Chlorine dioxide (CIO2) is a disinfectant used to treat municipal wastewater. When dissolved in alkaline solution, CIO3 and ClO,¯ are produced as shown in the reaction below. 2CIO, (aq) + 20H (aq)→ ClO,¯ (aq) + ClO,¯ (aq) + H,0 (1) 2C10, (aq) + 20H (aq)→ Cl0,¯ (aq) + ClO,¯ (aq) +H,0 (1) Consider the following data that were collected for this reaction. Exp [10,]nit, M [OH ]initr M Initial Rate, M/s Temperature, °C 1 0.020 0.050 1.4 X 10-3 25.0 2 0.020 0.100 2.8 X 10-3 25.0 3 0.010 0.050 7.0 X 104 25.0 0.020 0.050 6.0 X 10-3 38.0 0.020 0.050 2.3 X 10-2 51.0 Exp [10, ]mt, M [OH Imitr M Initial Rate, M/s Temperature, ºC 1 0.020 0.050 1.4 X 10-3 25.0 0.020 0.100 2.8 X 10-3 25.0 0.010 0.050 7.0 X 10-4 25.0 4 0.020 0.050 6.0X 10-3 38.0 0.020 0.050 2.3 X 10-2 51.0 Question 1 Determine the reaction order with respect to ClO, (aq) and OH- (aq). Exp [C0,]mitr M [OH ]mit, M Initial Rate, M/s Temperature, ºc 1 0.020 0.050 1.4 X 10-3 25.0 0.020 0.100 2.8 X 10-3 25.0 0.010 0.050 7.0 X 10-4 25.0 4 0.020 0.050 6.0 X 10-3 38.0 5 0.020 0.050 2.3 X 10-2 51.0
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