Use MO theory to explain the following: - TT 2p 2р, 2р, 2р, 2р, 2px 2ру 2pz 2px 2Py 2pz 2px 2py TT2P TT 2p 02s 2s 2s 2s 2s 02s 02s i. The first and second ionization energies of 02 are similar to each other at ~1200 kJ/mol, while the third ionization energy of 02 is significantly greater at ~1600 kJ/mol. ii. Although there are more electrons available to create bonds in F, than in 02, the bond dissociation energy is much smaller in F2 than in 02. iii. the longest wavelength of light that can be absorbed by 02 is ~100 nm. (No calculations are required for this). The longest wavelength of light that can be absorbed by N2 is ~80 nm, while

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Chapter1: Chemical Foundations
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Use MO theory to explain the following:
-
TT 2p
2р, 2р, 2р,
2р, 2px 2ру
2pz 2px 2Py
2pz 2px 2py
TT2P
TT 2p
02s
2s
2s
2s
2s
02s
02s
i. The first and second ionization energies of 02 are similar to each other at
~1200 kJ/mol, while the third ionization energy of 02 is significantly greater at
~1600 kJ/mol.
ii. Although there are more electrons available to create bonds in F, than in 02,
the bond dissociation energy is much smaller in F2 than in 02.
iii.
the longest wavelength of light that can be absorbed by 02 is ~100 nm. (No
calculations are required for this).
The longest wavelength of light that can be absorbed by N2 is ~80 nm, while
Transcribed Image Text:Use MO theory to explain the following: - TT 2p 2р, 2р, 2р, 2р, 2px 2ру 2pz 2px 2Py 2pz 2px 2py TT2P TT 2p 02s 2s 2s 2s 2s 02s 02s i. The first and second ionization energies of 02 are similar to each other at ~1200 kJ/mol, while the third ionization energy of 02 is significantly greater at ~1600 kJ/mol. ii. Although there are more electrons available to create bonds in F, than in 02, the bond dissociation energy is much smaller in F2 than in 02. iii. the longest wavelength of light that can be absorbed by 02 is ~100 nm. (No calculations are required for this). The longest wavelength of light that can be absorbed by N2 is ~80 nm, while
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