Homework Help is Here – Start Your Trial Now!
Engineering
Chemical Engineering
2.15 Huang and Dauerman (1969) have studied the acetylation of benzyl chloride (C6HSCH2C1) in dilute solution at 102°C. Using equimolal concentrations of sodium acetate (NaAc) and benzyl chloride (0.75 kmol/m'), the table below lists the reported data on the fraction of benzyl chloride remaining unconverted as function of time. Determine the order of the reaction and the reaction rate constant at this temperature. Time, ksec CB/CB0B where B CoH;CH2CI 10.80 0.945 24.48 0.912 46.08 0.846 0.809 54.72 69.48 0.779 0.730 88.56 0.678 109.44 0.638 126.72 0.619 133.74 0.590 140.76 The acetylation reaction is represented thus: k C,H,CH,Cl + NaAc-C >C,H,CH,Ac+ Na" +Cl CH.COOCH, + H,0->CH,COOH +CH,OH 2.15 Huang and Dauerman (1969) have studied the acetylation of benzyl chloride (C6HSCH2CI) in dilute solution at 102°C. Using equimolal concentrations of sodium acetate (NaAc) and benzyl chloride (0.75 kmol/m'), the table below lists the reported data on the fraction of benzyl chloride remaining unconverted as function of time. Determine the order of the reaction and the reaction rate constant at this temperature. Time, ksec CelCBoB where B C6H;CH;CI 10.80 0.945 24.48 0.912 46.08 0.846 54.72 0.809 69.48 0.779 88.56 0.730 109.44 0.678 126.72 0.638 133.74 0.619 140.76 0.590 The acetylation reaction is represented thus: C,H,CH,Cl+ NaAc->C,H,CH, Ac + Na" +CI

2.15 Huang and Dauerman (1969) have studied the acetylation of benzyl chloride (C6HSCH2C1) in dilute solution at 102°C. Using equimolal concentrations of sodium acetate (NaAc) and benzyl chloride (0.75 kmol/m'), the table below lists the reported data on the fraction of benzyl chloride remaining unconverted as function of time. Determine the order of the reaction and the reaction rate constant at this temperature. Time, ksec CB/CB0B where B CoH;CH2CI 10.80 0.945 24.48 0.912 46.08 0.846 0.809 54.72 69.48 0.779 0.730 88.56 0.678 109.44 0.638 126.72 0.619 133.74 0.590 140.76 The acetylation reaction is represented thus: k C,H,CH,Cl + NaAc-C >C,H,CH,Ac+ Na" +Cl CH.COOCH, + H,0->CH,COOH +CH,OH 2.15 Huang and Dauerman (1969) have studied the acetylation of benzyl chloride (C6HSCH2CI) in dilute solution at 102°C. Using equimolal concentrations of sodium acetate (NaAc) and benzyl chloride (0.75 kmol/m'), the table below lists the reported data on the fraction of benzyl chloride remaining unconverted as function of time. Determine the order of the reaction and the reaction rate constant at this temperature. Time, ksec CelCBoB where B C6H;CH;CI 10.80 0.945 24.48 0.912 46.08 0.846 54.72 0.809 69.48 0.779 88.56 0.730 109.44 0.678 126.72 0.638 133.74 0.619 140.76 0.590 The acetylation reaction is represented thus: C,H,CH,Cl+ NaAc->C,H,CH, Ac + Na" +CI

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
See similar textbooks
icon
Related questions
Question
2.15 Huang and Dauerman (1969) have studied the acetylation of benzyl chloride (C6HSCH2C1) in dilute solution at 102°C. Using equimolal concentrations of sodium acetate (NaAc) and benzyl chloride (0.75 kmol/m'), the table below lists the reported data on the fraction of benzyl chloride remaining unconverted as function of time. Determine the order of the reaction and the reaction rate constant at this temperature. Time, ksec CB/CB0B where B CoH;CH2CI 10.80 0.945 24.48 0.912 46.08 0.846 0.809 54.72 69.48 0.779 0.730 88.56 0.678 109.44 0.638 126.72 0.619 133.74 0.590 140.76 The acetylation reaction is represented thus: k C,H,CH,Cl + NaAc-C >C,H,CH,Ac+ Na" +Cl
Transcribed Image Text:2.15 Huang and Dauerman (1969) have studied the acetylation of benzyl chloride (C6HSCH2C1) in dilute solution at 102°C. Using equimolal concentrations of sodium acetate (NaAc) and benzyl chloride (0.75 kmol/m'), the table below lists the reported data on the fraction of benzyl chloride remaining unconverted as function of time. Determine the order of the reaction and the reaction rate constant at this temperature. Time, ksec CB/CB0B where B CoH;CH2CI 10.80 0.945 24.48 0.912 46.08 0.846 0.809 54.72 69.48 0.779 0.730 88.56 0.678 109.44 0.638 126.72 0.619 133.74 0.590 140.76 The acetylation reaction is represented thus: k C,H,CH,Cl + NaAc-C >C,H,CH,Ac+ Na" +Cl
CH.COOCH, + H,0->CH,COOH +CH,OH 2.15 Huang and Dauerman (1969) have studied the acetylation of benzyl chloride (C6HSCH2CI) in dilute solution at 102°C. Using equimolal concentrations of sodium acetate (NaAc) and benzyl chloride (0.75 kmol/m'), the table below lists the reported data on the fraction of benzyl chloride remaining unconverted as function of time. Determine the order of the reaction and the reaction rate constant at this temperature. Time, ksec CelCBoB where B C6H;CH;CI 10.80 0.945 24.48 0.912 46.08 0.846 54.72 0.809 69.48 0.779 88.56 0.730 109.44 0.678 126.72 0.638 133.74 0.619 140.76 0.590 The acetylation reaction is represented thus: C,H,CH,Cl+ NaAc->C,H,CH, Ac + Na" +CI
Transcribed Image Text:CH.COOCH, + H,0->CH,COOH +CH,OH 2.15 Huang and Dauerman (1969) have studied the acetylation of benzyl chloride (C6HSCH2CI) in dilute solution at 102°C. Using equimolal concentrations of sodium acetate (NaAc) and benzyl chloride (0.75 kmol/m'), the table below lists the reported data on the fraction of benzyl chloride remaining unconverted as function of time. Determine the order of the reaction and the reaction rate constant at this temperature. Time, ksec CelCBoB where B C6H;CH;CI 10.80 0.945 24.48 0.912 46.08 0.846 54.72 0.809 69.48 0.779 88.56 0.730 109.44 0.678 126.72 0.638 133.74 0.619 140.76 0.590 The acetylation reaction is represented thus: C,H,CH,Cl+ NaAc->C,H,CH, Ac + Na" +CI
Expert Solution
steps

Step by step

Solved in 3 steps with 3 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The
SEE MORE TEXTBOOKS