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- Write balanced net-ionic equations to describe: (a) the reduction of Fe3+ to Fe2+ by SO2 (b) the reaction of H2MoO4 in a Jones reductor (c) the oxidation of HNO2 by a solution of MnO-4. (d) The reaction of aniline (C6H4NH2) with a mixture of KBrO3 and KBr in acidic solution (e) the air oxidation of HAsO2-3 to HasO2-4 (f) the reaction of KI with HNO2 in acidic solutionWrite balanced net-ionic equations to describe: (a) the reduction of Fe3+ to Fe2+ by SO2 (b) the reaction of H2MoO4 in a Jones reductor (c) the oxidation of HNO2 by a solution of MnO-4. (d) The reaction of aniline (C6H4NH2) with a mixture of KBrO3 and KBr in acidic solution (e) the air oxidation of HAsO2-3 to HasO2-4 (f) the reaction of KI with HNO2 in acidic solution Please answer letters d, e, and fIn each of the following cases give the name or structure of one compound which fits the information given. Explain your reasoning and write equations for the reactions involved. (a)R is a liquid which reacts vigorously with concentrated aqueous ammonia to form a solid which is readily dehydrated by warming with phosphorus(v) oxide. (b)S is a liquid which dissolves in hot aqueous sodium hydroxide to form a solution which on cooling and acidifying precipitates a white solid. A solution of this solid evolves carbon(IV) oxide with aqueous sodium carbonate
- In each of the following cases give the name or structure of one compound which fits the information given.Explain your reasoning and write equations for the reactions involved. (a)R is a liquid which reacts vigorously with concentrated aqueous ammonia to form a solid which is readily dehydrated by warming with phosphorus(v) oxide. (b)S is a liquid which dissolves in hot aqueous sodium hydroxide to form a solution which on cooling and acidifying precipitates a white solid. A solution of this solid evolves carbon(iv)oxide with aqueous sodium carbonate.Explain the following observations: (a) For a given oxidationstate, the acid strength of the oxyacid in aqueous solutiondecreases in the order chlorine > bromine > iodine.(b) Hydrofluoric acid cannot be stored in glass bottles.(c) HI cannot be prepared by treating NaI with sulfuricacid. (d) The interhalogen ICl3 is known, but BrCl3 is not.Describe the conditions to be maintained during the titration of a permanganate solution with oxalate. Detail the chemical principles involved.
- (a) Provide the chemical structures of the products (3) and (4). (i) Ph3P Br (3) (4) (ii) NaHFor Iron (Fe) Account for the stabilities of the oxidation states toward reduction and/or oxidation, including any variation of stability with pH or complex formation. full explanationYou have been sent to India to investigate the occurence of goiter disease attributed to iodine deficency. As part of of your investigation, you must make field measurements of traces of Iodide(I-) in groundwater. The procedure is to oxidize I- to I2 and convert the I2 into an intensely colored complex with the dye brilliant green in the organic solvent toluene. a) A 3.15x10^-6 M solution of the colored complex exhibited an absorbance of 0.267 at 635nm in a 1.00cm cuvet. A blank solution made from distilled water in place of groundwater had an absorbance of 0.019. Find the molar absroptivity of the colored complex. b)The absorbance of an unknown solution prepared from ground water was 0.175. Find the concentration of the unknown.
- Describe the following by giving a suitable example in each case : (a) minimum boiling azeotropes (b) maximum boiling azetropesExplain how (the dreaded chemistry) the addition of alum decreases alkalinity and tends to lower the pH of the treated water. (you may want to have a separate slide or graphic to help you explain this).Discuss the preparation, properties anduses of(a) Celluloid