CHAPTER 3. Volumetric Properties of Pure Fluids 24 3.42. For methyl chloride at 100°C the second and third virial coefficients are: B -242.5 cm3.mol -1 C= 25,200 cmo.mol- Calculate the work of mechanically reversible, isothermal compression of 1 mol of methyl chloride from 1 bar to 55 bar at 100°C. Base calculations on the following forms of the virial equation: tot В С + V 32(a) ताी deal z=1+tv V2 (b) Z 1 B'P + C'P2 E0.0- Grst 130 С -В2 В and C'= В'" where ro boap A BEE 11 (RT)2 RT faups nisinos Why don't both equations give exactly the same result? HOS & BRIGE als A C 1 43 44

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CHAPTER 3. Volumetric Properties of Pure Fluids
24
3.42. For methyl chloride at 100°C the second and third virial coefficients are:
B -242.5 cm3.mol -1 C= 25,200 cmo.mol-
Calculate the work of mechanically reversible, isothermal compression of 1 mol of
methyl chloride from 1 bar to 55 bar at 100°C. Base calculations on the following
forms of the virial equation:
tot
В С
+
V
32(a)
ताी
deal
z=1+tv
V2
(b)
Z 1 B'P + C'P2
E0.0-
Grst
130
С -В2
В
and C'=
В'"
where
ro boap A BEE
11
(RT)2
RT
faups nisinos
Why don't both equations give exactly the same result?
HOS & BRIGE
als A
C
1
43
44
Transcribed Image Text:CHAPTER 3. Volumetric Properties of Pure Fluids 24 3.42. For methyl chloride at 100°C the second and third virial coefficients are: B -242.5 cm3.mol -1 C= 25,200 cmo.mol- Calculate the work of mechanically reversible, isothermal compression of 1 mol of methyl chloride from 1 bar to 55 bar at 100°C. Base calculations on the following forms of the virial equation: tot В С + V 32(a) ताी deal z=1+tv V2 (b) Z 1 B'P + C'P2 E0.0- Grst 130 С -В2 В and C'= В'" where ro boap A BEE 11 (RT)2 RT faups nisinos Why don't both equations give exactly the same result? HOS & BRIGE als A C 1 43 44
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