Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![## Exploring Conformations of Butane
### Structure of Butane
The chemical structure of butane is depicted as:
\[ \text{CH}_3 - \text{CH}_2 - \text{CH} - \text{CH}_3 \]
### Newman Projections of Butane
Three Newman projections are shown to illustrate different conformations of butane.
1. **Most Stable Conformation:**
- The leftmost diagram shows the most stable conformation of butane.
- In this conformation, the methyl groups (\( \text{CH}_3 \)) and hydrogens (H) are spaced to minimize gauche interactions.
- The statement below reads: "Most Stable - It has the least gauche interactions."
2. **Intermediary Conformation:**
- The central diagram represents an intermediary conformation that is less stable than the first but more stable than the eclipsed conformation.
- This configuration is indicated with bidirectional arrows showing possible rotation.
3. **Least Stable Conformation:**
- The rightmost diagram illustrates the least stable conformation.
- Here, the methyl groups (\( \text{CH}_3 \)) are aligned, leading to maximum eclipse.
- The statement below reads: "Least Stable - eclipsed configuration."
This sequence of diagrams helps in understanding the rotational energy barrier in butane due to steric hindrance and torsional strain, which affects its stability.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd316c604-bbbc-4ee5-b52e-cb7185977a9a%2Fe20dc04f-63c5-4c96-8aba-6d485a62d9ff%2Foib734r_processed.jpeg&w=3840&q=75)
Transcribed Image Text:## Exploring Conformations of Butane
### Structure of Butane
The chemical structure of butane is depicted as:
\[ \text{CH}_3 - \text{CH}_2 - \text{CH} - \text{CH}_3 \]
### Newman Projections of Butane
Three Newman projections are shown to illustrate different conformations of butane.
1. **Most Stable Conformation:**
- The leftmost diagram shows the most stable conformation of butane.
- In this conformation, the methyl groups (\( \text{CH}_3 \)) and hydrogens (H) are spaced to minimize gauche interactions.
- The statement below reads: "Most Stable - It has the least gauche interactions."
2. **Intermediary Conformation:**
- The central diagram represents an intermediary conformation that is less stable than the first but more stable than the eclipsed conformation.
- This configuration is indicated with bidirectional arrows showing possible rotation.
3. **Least Stable Conformation:**
- The rightmost diagram illustrates the least stable conformation.
- Here, the methyl groups (\( \text{CH}_3 \)) are aligned, leading to maximum eclipse.
- The statement below reads: "Least Stable - eclipsed configuration."
This sequence of diagrams helps in understanding the rotational energy barrier in butane due to steric hindrance and torsional strain, which affects its stability.
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