Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can you please draw out a complete curve arrow mechanism with the reagent and intermediate steps?

Transcribed Image Text:### Understanding the Glyoxylate Cycle: Key Reactions in Plant Metabolism
#### A Step in the Glyoxylate Cycle
The glyoxylate cycle is an essential biochemical pathway in plants that allows them to convert fats into sugars, especially important for seed germination and young plants before they begin photosynthesis. Below is a detailed diagram representing one of the critical steps in the glyoxylate cycle.
#### Diagram Explanation
**Isocitrate to Glyoxylate and Succinate Conversion**
The reaction involves the conversion of *Isocitrate* into *Glyoxylate* and *Succinate*. This process is catalyzed by the enzyme isocitrate lyase.
1. **Isocitrate**: Isocitrate is an intermediate in the citric acid cycle. Its molecular structure includes six carbon atoms, three carboxyl groups (-COOH), and one hydroxyl group (-OH).
2. **Glyoxylate**: This is a two-carbon molecule formed as one of the products in this reaction. Its structure includes one aldehyde group (-CHO) and one carboxyl group (-COOH).
3. **Succinate**: This four-carbon molecule is another product of this reaction and includes two carboxyl groups (-COOH) on each end of its chain.
The reaction is depicted as follows:
```
O O
|| ||
HO-C-CH -> HO-CH-C + HO-C-CH-CH-COOH
| || ||
CH2 O O
Isocitrate Glyoxylate Succinate
```
- The arrow indicates the direction of the reaction catalyzed by isocitrate lyase.
By understanding this step in the glyoxylate cycle, one can appreciate how plants efficiently manage their resources, particularly in converting stored fats into sugars necessary for growth and development.
---
For further exploration, students are encouraged to study the entire glyoxylate cycle and its role in plant metabolism, along with the enzymes involved in each step.
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