Calculate the pH at the equivalence point in titrating 0.020 M solutions of each of the following with 0.039 M NaOH. (a) perchloric acid (HCIO 4) pH =
Calculate the pH at the equivalence point in titrating 0.020 M solutions of each of the following with 0.039 M NaOH. (a) perchloric acid (HCIO 4) pH =
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Calculate the pH at the equivalence point in titrating 0.020 M solutions of each of the following with 0.039 M NaOH.**
(a) **Perchloric acid (HClO₄)**
pH = _______
(b) **Hydrazoic acid (HN₃), Kₐ = 1.9e-05**
pH = _______
(c) **Carbonic acid (H₂CO₃), Kₐ = 4.3e-07**
pH = _______
This section provides exercises on calculating the pH at the equivalence point for titrations involving perchloric acid, hydrazoic acid, and carbonic acid. The titrations are done using a 0.039 M NaOH solution. It includes the acid dissociation constants (Kₐ) for weak acids to assist with the calculations.
Expert Solution

Step 1
pH is the power of hydronium ion concentration. It is used to measure the acidity or alkalinity of a substance. For acidic substances, the pH value is less than 7 and for bases, it is more than 7. If the pH is 7, the substance is neutral.
Given: The concentration of HClO4, HN3, and H2CO3 is 0.020 M and the concentration of NaOH is 0.039 M. The value of Ka (acid dissociation constant) for hydrazine (HN3) is , and for carbonic acid (H2CO3) is .
To calculate: pH
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