Calculate the pH of 1.00 L of the buffer 0.92 M CH3COONa/0.97 M CH3COOH before and after the addition of the following species. (Assume there is no change in volume.) (a) pH of starting buffer: (b) pH after addition of 0.085 mol NaOH: (c) pH after further addition of 0.120 mol HCl:

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Help please
**Calculate the pH of 1.00 L of the buffer 0.92 M CH₃COONa/0.97 M CH₃COOH before and after the addition of the following species. (Assume there is no change in volume.)**

(a) pH of starting buffer:
- [ ] 

(b) pH after addition of 0.085 mol NaOH:
- [ ]

(c) pH after further addition of 0.120 mol HCl:
- [ ] 

**Explanation of pH Calculations:**

- **Starting Buffer:** Use the Henderson-Hasselbalch equation to calculate the initial pH using the concentrations of CH₃COONa and CH₃COOH.
  
- **Addition of NaOH:** The addition of NaOH will react with CH₃COOH, increasing the concentration of CH₃COONa and altering the buffer ratio. Calculate the new pH using the updated concentrations.

- **Further Addition of HCl:** The added HCl will react with CH₃COO⁻ ions, increasing CH₃COOH. Recalculate the pH with the modified buffer concentrations.

This set of calculations demonstrates buffer capacity and the effect of adding strong acids and bases to a buffer solution.
Transcribed Image Text:**Calculate the pH of 1.00 L of the buffer 0.92 M CH₃COONa/0.97 M CH₃COOH before and after the addition of the following species. (Assume there is no change in volume.)** (a) pH of starting buffer: - [ ] (b) pH after addition of 0.085 mol NaOH: - [ ] (c) pH after further addition of 0.120 mol HCl: - [ ] **Explanation of pH Calculations:** - **Starting Buffer:** Use the Henderson-Hasselbalch equation to calculate the initial pH using the concentrations of CH₃COONa and CH₃COOH. - **Addition of NaOH:** The addition of NaOH will react with CH₃COOH, increasing the concentration of CH₃COONa and altering the buffer ratio. Calculate the new pH using the updated concentrations. - **Further Addition of HCl:** The added HCl will react with CH₃COO⁻ ions, increasing CH₃COOH. Recalculate the pH with the modified buffer concentrations. This set of calculations demonstrates buffer capacity and the effect of adding strong acids and bases to a buffer solution.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps with 3 images

Blurred answer
Knowledge Booster
Acid-Base Titrations
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY