Calculate the pH of 1.00 L of the buffer 0.92 M CH3COONa/0.97 M CH3COOH before and after the addition of the following species. (Assume there is no change in volume.) (a) pH of starting buffer: (b) pH after addition of 0.085 mol NaOH: (c) pH after further addition of 0.120 mol HCl:
Calculate the pH of 1.00 L of the buffer 0.92 M CH3COONa/0.97 M CH3COOH before and after the addition of the following species. (Assume there is no change in volume.) (a) pH of starting buffer: (b) pH after addition of 0.085 mol NaOH: (c) pH after further addition of 0.120 mol HCl:
Chemistry
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Chapter1: Chemical Foundations
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![**Calculate the pH of 1.00 L of the buffer 0.92 M CH₃COONa/0.97 M CH₃COOH before and after the addition of the following species. (Assume there is no change in volume.)**
(a) pH of starting buffer:
- [ ]
(b) pH after addition of 0.085 mol NaOH:
- [ ]
(c) pH after further addition of 0.120 mol HCl:
- [ ]
**Explanation of pH Calculations:**
- **Starting Buffer:** Use the Henderson-Hasselbalch equation to calculate the initial pH using the concentrations of CH₃COONa and CH₃COOH.
- **Addition of NaOH:** The addition of NaOH will react with CH₃COOH, increasing the concentration of CH₃COONa and altering the buffer ratio. Calculate the new pH using the updated concentrations.
- **Further Addition of HCl:** The added HCl will react with CH₃COO⁻ ions, increasing CH₃COOH. Recalculate the pH with the modified buffer concentrations.
This set of calculations demonstrates buffer capacity and the effect of adding strong acids and bases to a buffer solution.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe8e7ecd1-00b2-4f87-97f4-1e990180b5ce%2F78885e33-0ab1-4a5b-9149-4379ce5269ac%2Fmobt4gg_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Calculate the pH of 1.00 L of the buffer 0.92 M CH₃COONa/0.97 M CH₃COOH before and after the addition of the following species. (Assume there is no change in volume.)**
(a) pH of starting buffer:
- [ ]
(b) pH after addition of 0.085 mol NaOH:
- [ ]
(c) pH after further addition of 0.120 mol HCl:
- [ ]
**Explanation of pH Calculations:**
- **Starting Buffer:** Use the Henderson-Hasselbalch equation to calculate the initial pH using the concentrations of CH₃COONa and CH₃COOH.
- **Addition of NaOH:** The addition of NaOH will react with CH₃COOH, increasing the concentration of CH₃COONa and altering the buffer ratio. Calculate the new pH using the updated concentrations.
- **Further Addition of HCl:** The added HCl will react with CH₃COO⁻ ions, increasing CH₃COOH. Recalculate the pH with the modified buffer concentrations.
This set of calculations demonstrates buffer capacity and the effect of adding strong acids and bases to a buffer solution.
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