Calculate the mass of the reaction mixture in each reaction. (To do this, first determine the total volume of the solution. Then calculate the mass of the solution, based on the assumption that the added solid does not change the volume and that the density of the solution is the same as that of pure water, 1.0 g/mL.) Remember to add the mass of the solid. a) Calculate the total heat released in each reaction, in J, assuming that the specific heat capacity of the solution is the same as that of pure water, 4.184 J/ºC g. Remember: heat of reaction = m C Δ T b) Calculate the number of moles of NaOH used in reactions 1 c) Calculate the number of moles of NaOH used in reaction 3 by multiplying the volume of NaOH times the molarity (1.000 mol/L). d)Calculate the energy released, in kJ/mol, of NaOH for each reaction.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
- Calculate the mass of the reaction mixture in each reaction. (To do this, first determine the total volume of the solution. Then calculate the mass of the solution, based on the assumption that the added solid does not change the volume and that the density of the solution is the same as that of pure water, 1.0 g/mL.) Remember to add the mass of the solid.
a) Calculate the total heat released in each reaction, in J, assuming that the specific heat capacity of the solution is the same as that of pure water, 4.184 J/ºC g. Remember: heat of reaction = m C Δ T
b) Calculate the number of moles of NaOH used in reactions 1
c) Calculate the number of moles of NaOH used in reaction 3 by multiplying the volume of NaOH times the molarity (1.000 mol/L).
d)Calculate the energy released, in kJ/mol, of NaOH for each reaction.
![Reaction 1
2. There will be a bottle of NaOH near the balance. A weigh paper will be on the balance with
approximately 4 g NaOH on the paper. Record the mass of NaOH in the data table on the
following page.
3. The calorimeter will be on the lab bench and filled with 200 mL water. Make certain the
stirrer is On (you should be able to see the shaft rotating). In the thermometer window click
Save to begin recording data. Allow 20-30 seconds to obtain a baseline temperature of the
water.
4. Drag the weigh paper with the sample to the calorimeter until it snaps into place and then
the sample into the calorimeter. Observe the change in temperature until it reaches a
maximum and then record data for an additional 20-30 seconds. Click Stop. (You can click on
the clock on the wall labeled Accelerate to accelerate the time in the laboratory.) A data link
icon will appear in the lab book. Click the data link icon and record the initial and final water
temperatures in the data table. If you need to repeat this part of the experiment, enter the
Stockroom and select the preset experiment called Heat of Solution-NaOH on the clipboard.
pour
Reaction 2
5. Click the red disposal bucket to clear the lab. Click on the Stockroom to enter. Click on the
clipboard and select the preset experiment called Heat of Reaction: HCl(ag) + NaOH(s).
Return to the laboratory.
6. There will be a bottle of NaOH near the balance. A weigh paper will be on the balance with
approximately 4 g NaOH on the paper. Record the mass of NaOH in the data table. The
calorimeter will be on the lab bench filled with 100 mL water, and there will be a beaker
containing 100 mL of 1.000 M HCl on the lab bench. In the thermometer window click Save
to begin recording data. Allow 20-30 seconds to obtain a baseline temperature of the water.
7. Make sure the beaker of HCl is visible and drag it to the calorimeter and pour it into the
calorimeter. The HCl and the water are at the same temperature so there should be no
temperature change. Now drag the weigh paper with the NaOH to the calorimeter until it
snaps into place and pour the sample into the calorimeter. It is important that the HCl be
added first and the NaOH added second. Observe the change in temperature until it reaches a
maximum and then record data for an additional 20-30 seconds. Record the temperature
before adding the HCl and the temperature after adding the NaOH in the data table.
Reaction 3
In the thermometer window click Save to begin recording data. Allow 20-30 seconds to obtain a
baseline temperature of the water. Pour the left beaker containing 100 mL of 1.0000M HCl into
the empty calorimeter and then pour the right beaker containing 100 mL of 1.0000M NAOH into](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbba86bae-0df4-478c-83cd-96583110af4f%2F6527fbf4-c44f-4f3a-877e-5872eadd83dd%2Fnbop5kg_processed.png&w=3840&q=75)
![Data Table
Parameter
Reaction 1 Reaction 2 Reaction 3
Mass NaOH
3.9983
4.0013
initial temperature (° C)
25
25
25
final temperature (° C)
30.21
35.07
31.07](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbba86bae-0df4-478c-83cd-96583110af4f%2F6527fbf4-c44f-4f3a-877e-5872eadd83dd%2Fzvfrk4s_processed.png&w=3840&q=75)
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