Calculate the M of the malonic in the sample.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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A 20 ml aliquot of malonic acid solution was treated with 10.0 ml of 0.25M Ce4+ leading to the reaction

         

     CH2(COOH)2  +  6Ce4+  +  2H2®  HCOOH  +  2CO2  +  6Ce3+  +  6H+

 

After standing for 10 minutes at 60oC, the solution was cooled and the x’ss Ce4+ was titrated with 0.1M Fe2+, requiring 14.4 ml to reach the ferroin end point. Calculate the M of the malonic in the sample.

A 20 ml aliquot of malonic acid solution was treated with 10.0 ml of 0.25M Ce4+ leading
to the reaction
CH2(COOH)2 + 6Ce4* + 2H20 → HCOOH + 2CO2 + 6Ce3* + 6H*
After standing for 10 minutes at 60°C, the solution was cooled and the x'ss Ce4+ was
titrated with 0.1M Fe2+, requiring 14.4 ml to reach the ferroin end point. Calculate the M
of the malonic in the sample.
Transcribed Image Text:A 20 ml aliquot of malonic acid solution was treated with 10.0 ml of 0.25M Ce4+ leading to the reaction CH2(COOH)2 + 6Ce4* + 2H20 → HCOOH + 2CO2 + 6Ce3* + 6H* After standing for 10 minutes at 60°C, the solution was cooled and the x'ss Ce4+ was titrated with 0.1M Fe2+, requiring 14.4 ml to reach the ferroin end point. Calculate the M of the malonic in the sample.
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