Calculate the coupling constant for all the signals (a-e) in Attachments A and B (b) Draw tree diagrams for all the signals (a-e) and label all the calculated coupling constant values into the tree diagrams (eg. Ja-b = 5.0 Hz) (c) Identify which of the structures (C or D) corresponds to the 1H NMR spectrum shown in the following pages. Explain your answer.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(a) Calculate the coupling constant for all the signals (a-e) in Attachments A and B

(b) Draw tree diagrams for all the signals (a-e) and label all the calculated coupling constant values into the tree diagrams (eg. Ja-b = 5.0 Hz)

(c) Identify which of the structures (C or D) corresponds to the 1H NMR spectrum shown in the following pages. Explain your answer.

H.
Compound C
Compound D
1H NMR Spectrum
a
e
(ppm)
Transcribed Image Text:H. Compound C Compound D 1H NMR Spectrum a e (ppm)
Attachment A
b
(ppm)
(ppm)
Attachment B
672
6.64
640
232
(ppm)
(ppm)
(ppm)
513.06
511.43
506.24
504.61
16'SRLE
Os ERLI -
EN'ILLI
90OLLI
- 263,88
- 256,47
Transcribed Image Text:Attachment A b (ppm) (ppm) Attachment B 672 6.64 640 232 (ppm) (ppm) (ppm) 513.06 511.43 506.24 504.61 16'SRLE Os ERLI - EN'ILLI 90OLLI - 263,88 - 256,47
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