Calculate [OH ], [H*], and the pH of 0.41 M solutions of each of the following amines (K, for aniline is 3.8 × 10-10, K½ for methylamine is 4.38 × 104). a. aniline [OH¯] =[ м [H*] = [ pH = b. methylamine [OH¯] = [ |M [H*] =[ M pH =

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

I am still stuck on this one

**Calculation of Hydroxide Ion Concentration \([OH^-]\), Hydrogen Ion Concentration \([H^+]\), and pH of Amine Solutions**

On this page, we demonstrate the process of calculating \( [OH^-] \), \( [H^+] \), and the pH of 0.41 M solutions of two different amines. We use the base dissociation constants (\( K_b \)) for each amine to facilitate these calculations.

Given:
- For aniline: \( K_b = 3.8 \times 10^{-10} \)
- For methylamine: \( K_b = 4.38 \times 10^{-4} \)

### a. Aniline

1. **Hydroxide Ion Concentration \([OH^-]\)**:
   
   Input area for result: \_\_\_\_\_\_ M

2. **Hydrogen Ion Concentration \([H^+]\)**:

   Input area for result: \_\_\_\_\_\_ M

3. **pH**:

   Input area for result: \_\_\_\_\_\_

### b. Methylamine

1. **Hydroxide Ion Concentration \([OH^-]\)**:
   
   Input area for result: \_\_\_\_\_\_ M

2. **Hydrogen Ion Concentration \([H^+]\)**:
   
   Input area for result: \_\_\_\_\_\_ M

3. **pH**:
   
   Input area for result: \_\_\_\_\_\_

For each amine, you can calculate the hydroxide ion concentration \([OH^-]\) using the \( K_b \) value and the initial concentration of the amine solution. Once \([OH^-]\) is determined, you can calculate \([H^+]\) using the water dissociation constant \( K_w = 1.0 \times 10^{-14} \) at 25°C. Finally, the pH of the solution can be calculated using the formula:

\[ \text{pH} = -\log [H^+] \]

This framework helps in understanding the influence of different \( K_b \) values on the pH of amine solutions.
Transcribed Image Text:**Calculation of Hydroxide Ion Concentration \([OH^-]\), Hydrogen Ion Concentration \([H^+]\), and pH of Amine Solutions** On this page, we demonstrate the process of calculating \( [OH^-] \), \( [H^+] \), and the pH of 0.41 M solutions of two different amines. We use the base dissociation constants (\( K_b \)) for each amine to facilitate these calculations. Given: - For aniline: \( K_b = 3.8 \times 10^{-10} \) - For methylamine: \( K_b = 4.38 \times 10^{-4} \) ### a. Aniline 1. **Hydroxide Ion Concentration \([OH^-]\)**: Input area for result: \_\_\_\_\_\_ M 2. **Hydrogen Ion Concentration \([H^+]\)**: Input area for result: \_\_\_\_\_\_ M 3. **pH**: Input area for result: \_\_\_\_\_\_ ### b. Methylamine 1. **Hydroxide Ion Concentration \([OH^-]\)**: Input area for result: \_\_\_\_\_\_ M 2. **Hydrogen Ion Concentration \([H^+]\)**: Input area for result: \_\_\_\_\_\_ M 3. **pH**: Input area for result: \_\_\_\_\_\_ For each amine, you can calculate the hydroxide ion concentration \([OH^-]\) using the \( K_b \) value and the initial concentration of the amine solution. Once \([OH^-]\) is determined, you can calculate \([H^+]\) using the water dissociation constant \( K_w = 1.0 \times 10^{-14} \) at 25°C. Finally, the pH of the solution can be calculated using the formula: \[ \text{pH} = -\log [H^+] \] This framework helps in understanding the influence of different \( K_b \) values on the pH of amine solutions.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Tools in Analytical Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY