Calcium carbonate is sparingly soluble in water. CACO:(s) = Ca²“(aq) + CO;² (aq) Kp = 3.4 x 109 Calculate the solubility of CaCO; in sea water containing 0.01 mol L-' of Ca²* ions. (a) (b) Given the additional information below and using the Henderson Hasselbalch equation, what is the major form of carbonate in sea water and why? pH sea water = 8.1 H;CO; pKa1 = 6.35 HCO, pK2 = 10.33 (c) Write down the relevant equilibria and explain why the actual solubility of calcium carbonate (4.6 × 10-7 mol L-') is higher than the value you determined in part (a)?
Calcium carbonate is sparingly soluble in water. CACO:(s) = Ca²“(aq) + CO;² (aq) Kp = 3.4 x 109 Calculate the solubility of CaCO; in sea water containing 0.01 mol L-' of Ca²* ions. (a) (b) Given the additional information below and using the Henderson Hasselbalch equation, what is the major form of carbonate in sea water and why? pH sea water = 8.1 H;CO; pKa1 = 6.35 HCO, pK2 = 10.33 (c) Write down the relevant equilibria and explain why the actual solubility of calcium carbonate (4.6 × 10-7 mol L-') is higher than the value you determined in part (a)?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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![Calcium carbonate is sparingly soluble in water.
CaCO:(s) = Ca²"(aq) + CO;²(aq) Kp= 3.4 x 109
(a)
Calculate the solubility of CaCO; in sea water containing 0.01 mol L-ª of Ca²* ions.
(b)
Given the additional information below and using the Henderson Hasselbalch equation,
what is the major form of carbonate in sea water and why?
pH sea water = 8.1
H2CO: pKai = 6.35
HCO; pK2 = 10.33
Write down the relevant equilibria and explain why the actual solubility of calcium
carbonate (4.6 x 10-7 mol L-') is higher than the value you determined in part (a)?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbd25fbd1-110e-42f3-924f-dadb53a2e55e%2F1a546002-10fc-40b5-b51b-031077d54d7b%2F0f5fdsi_processed.png&w=3840&q=75)
Transcribed Image Text:Calcium carbonate is sparingly soluble in water.
CaCO:(s) = Ca²"(aq) + CO;²(aq) Kp= 3.4 x 109
(a)
Calculate the solubility of CaCO; in sea water containing 0.01 mol L-ª of Ca²* ions.
(b)
Given the additional information below and using the Henderson Hasselbalch equation,
what is the major form of carbonate in sea water and why?
pH sea water = 8.1
H2CO: pKai = 6.35
HCO; pK2 = 10.33
Write down the relevant equilibria and explain why the actual solubility of calcium
carbonate (4.6 x 10-7 mol L-') is higher than the value you determined in part (a)?
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