cal Kinetics when the concentration of X is 0.30 M and that of Y is 0.40 M. r moment during the reacting at the rate of is NO2 being formed? oxygen reacting? ems, ki- behav- [Y] (M) Initial Rate of [X] (M) ution of Disappearance of X (M/s) 0.50 Лoore, a - 2NH3(g) 0.10 0.053 ne num- 0.30 0.20 roughly Moore's 0.127 moment during the n is reacting at the hat rate is ammonia 0.60 0.40 1.02 0.60 0.20 reral de- 0.254 vn here th in the 0.30 te is molecular nitro- 0.40 0.509 circuit 13.17 Determine the overall orders of the reactions to which k[NO,J², k, (c) rate = k[H2] [Br2]³, (d) rate es it tak the following rate laws apply: (a) rate = ues unti (b) rate = k[NO]° [O2]. = imber o ar 2100 te law of a reaction. 13.18 Consider the reaction e constants of zero- der reactions? A B on: A product. action. (b) What are O Plot the rate of the The rate of the reaction is 1.6 x 10 M/s when the concentration of A is 0.35 M. Calculate the rate con- -2 stant if the reaction is (a) first order in A, and (b) second order in A. erties does the rate 13.19 Cyclobutane decomposes to ethylene according o the equation a) reactant concen- 2010 r (c) temperature? C,Hs(g) 2C,Hg) Determine the order of the reaction and the rate con- stant based on the following pressures, which were recorded when the reaction was carried out at 430°C in a constant-volume vessel. g) + 2H,O(1) At 25°C, the rate late the rate of the 330.26 M and Time (s) PCAHs (mmHg) %D 400 2,000 316 culate the rate of 130.010 M and 4,000 248 %3D 6,000 196 8,000 155 10,000 122 ts 13.20 The following gas-phase reaction was studied at 290°C by observing the change in pressure as a function of time in a constant-volume vessel: at a certain tem- reaction and cal-

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13.17

cal Kinetics
when the concentration of X is 0.30 M and that of
Y is 0.40 M.
r moment during the
reacting at the rate of
is NO2 being formed?
oxygen reacting?
ems, ki-
behav-
[Y] (M)
Initial Rate of
[X] (M)
ution of
Disappearance of X (M/s)
0.50
Лoore, a
- 2NH3(g)
0.10
0.053
ne num-
0.30
0.20
roughly
Moore's
0.127
moment during the
n is reacting at the
hat rate is ammonia
0.60
0.40
1.02
0.60
0.20
reral de-
0.254
vn here
th in the
0.30
te is molecular nitro-
0.40
0.509
circuit
13.17 Determine the overall orders of the reactions to which
k[NO,J²,
k, (c) rate = k[H2] [Br2]³, (d) rate
es it tak
the following rate laws apply: (a) rate =
ues unti
(b) rate =
k[NO]° [O2].
=
imber o
ar 2100
te law of a reaction.
13.18
Consider the reaction
e constants of zero-
der reactions?
A B
on: A product.
action. (b) What are
O Plot the rate of the
The rate of the reaction is 1.6 x 10 M/s when the
concentration of A is 0.35 M. Calculate the rate con-
-2
stant if the reaction is (a) first order in A, and
(b) second order in A.
erties does the rate
13.19 Cyclobutane decomposes to ethylene according o
the equation
a) reactant concen-
2010
r (c) temperature?
C,Hs(g)
2C,Hg)
Determine the order of the reaction and the rate con-
stant based on the following pressures, which were
recorded when the reaction was carried out at 430°C
in a constant-volume vessel.
g) + 2H,O(1)
At 25°C, the rate
late the rate of the
330.26 M and
Time (s)
PCAHs (mmHg)
%D
400
2,000
316
culate the rate of
130.010 M and
4,000
248
%3D
6,000
196
8,000
155
10,000
122
ts
13.20 The following gas-phase reaction was studied at
290°C by observing the change in pressure as a
function of time in a constant-volume vessel:
at a certain tem-
reaction and cal-
Transcribed Image Text:cal Kinetics when the concentration of X is 0.30 M and that of Y is 0.40 M. r moment during the reacting at the rate of is NO2 being formed? oxygen reacting? ems, ki- behav- [Y] (M) Initial Rate of [X] (M) ution of Disappearance of X (M/s) 0.50 Лoore, a - 2NH3(g) 0.10 0.053 ne num- 0.30 0.20 roughly Moore's 0.127 moment during the n is reacting at the hat rate is ammonia 0.60 0.40 1.02 0.60 0.20 reral de- 0.254 vn here th in the 0.30 te is molecular nitro- 0.40 0.509 circuit 13.17 Determine the overall orders of the reactions to which k[NO,J², k, (c) rate = k[H2] [Br2]³, (d) rate es it tak the following rate laws apply: (a) rate = ues unti (b) rate = k[NO]° [O2]. = imber o ar 2100 te law of a reaction. 13.18 Consider the reaction e constants of zero- der reactions? A B on: A product. action. (b) What are O Plot the rate of the The rate of the reaction is 1.6 x 10 M/s when the concentration of A is 0.35 M. Calculate the rate con- -2 stant if the reaction is (a) first order in A, and (b) second order in A. erties does the rate 13.19 Cyclobutane decomposes to ethylene according o the equation a) reactant concen- 2010 r (c) temperature? C,Hs(g) 2C,Hg) Determine the order of the reaction and the rate con- stant based on the following pressures, which were recorded when the reaction was carried out at 430°C in a constant-volume vessel. g) + 2H,O(1) At 25°C, the rate late the rate of the 330.26 M and Time (s) PCAHs (mmHg) %D 400 2,000 316 culate the rate of 130.010 M and 4,000 248 %3D 6,000 196 8,000 155 10,000 122 ts 13.20 The following gas-phase reaction was studied at 290°C by observing the change in pressure as a function of time in a constant-volume vessel: at a certain tem- reaction and cal-
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