C3 (5 mol%). CH2C,, 96 h, r.t. iPr `NO2 5b NO2 (S)-6b 83%, 97:3 e.r. .CO2H HO,C. CO,H 6N HCI Raney Ni, H2 AcОН, 48 h reflux, 28 h NH2 NH2.HCI 9, 90% (overall 52%) 8, 70%
C3 (5 mol%). CH2C,, 96 h, r.t. iPr `NO2 5b NO2 (S)-6b 83%, 97:3 e.r. .CO2H HO,C. CO,H 6N HCI Raney Ni, H2 AcОН, 48 h reflux, 28 h NH2 NH2.HCI 9, 90% (overall 52%) 8, 70%
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:C3 (5 mol%).
CH,C2, 96 h, r.t.
iPr
`NO2
5b
NO2
(S)-6b
83%, 97:3 e.r.
CO,H
HO,C.
CO2H
6N HCI
Raney Ni, H2
AcОН, 48 h
reflux, 28 h
NH2
NH2. HCI
9, 90%
(overall 52%)
8, 70%
Draw mechanisms for each reaction to form
compounds 6b, 8, and 9
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