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(c) H OH Co ayo OH (e) "&=&=& NH3 (aq) H MeOOC OH HA, - H₂O OH COOMe - HA "&&& HO OH H A 1) LiAlH₂O 2) H₂O+ MeOOC COOMe Any ester where ethylene glycol displaces methanol (hy transesterification) will be HOH2C Ac₂0 pyridine CH₂OAC AcOH2C CH₂OH Aqueous acid workup removes acetal (ketal)

(c) H OH Co ayo OH (e) "&=&=& NH3 (aq) H MeOOC OH HA, - H₂O OH COOMe - HA "&&& HO OH H A 1) LiAlH₂O 2) H₂O+ MeOOC COOMe Any ester where ethylene glycol displaces methanol (hy transesterification) will be HOH2C Ac₂0 pyridine CH₂OAC AcOH2C CH₂OH Aqueous acid workup removes acetal (ketal)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(c) (e) MeOOC H H H "&=&=& Ag+ NH3 (aq) OH OH OH axo. Cl HO OH HA, - H₂O COOMe OH O HA A - H₂O 1) LiAlH₂016 2) H3O+ MeOOC COOMe Any ester where ethylene glycol displaces methanol (by transesterification) will be reduced with LiAlH4. Ac₂0 pyridine HOH₂C CH₂OH Aqueous acid workup removes acetal (ketal) protecting group. AcOH2C CH₂OAc
Transcribed Image Text:(c) (e) MeOOC H H H "&=&=& Ag+ NH3 (aq) OH OH OH axo. Cl HO OH HA, - H₂O COOMe OH O HA A - H₂O 1) LiAlH₂016 2) H3O+ MeOOC COOMe Any ester where ethylene glycol displaces methanol (by transesterification) will be reduced with LiAlH4. Ac₂0 pyridine HOH₂C CH₂OH Aqueous acid workup removes acetal (ketal) protecting group. AcOH2C CH₂OAc
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