By analyzing the starting material and the product(s), the following reaction is an example of what type of mechanism? + SH- + Br Br SH а. Е1 b. S1 с. Е2 d. S,2 Predict the major product(s) of the following reaction: hv ? Br2 Br Br »Br Br II II IV V a. none of these b. Il and IV c. Il and V d. I and IV e. I only What type of bond cleavage does the following reaction involve? (CH3)3CB → (CH3)3C+ + Br¯

Chemistry
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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By analyzing the starting material and the product(s), the following reaction is an example
of what type of mechanism?
+ SH-
+ Br
Br
SH
а. Е1
b. S,1
с. Е2
d. S,2
Predict the major product(s) of the following reaction:
hv
?
Br2
Bre
Br
Br
Br
II
II
IV
V
a. none of these
b. Il and IV
c. Il and V
d. I and IV
e. I only
What type of bond cleavage does the following reaction involve?
(CH3)3CB → (CH3)3C+ + Br¯
a. lonic
b. covalent
c. free radical
d. heterolytic
e. homolytic
%3D
Transcribed Image Text:By analyzing the starting material and the product(s), the following reaction is an example of what type of mechanism? + SH- + Br Br SH а. Е1 b. S,1 с. Е2 d. S,2 Predict the major product(s) of the following reaction: hv ? Br2 Bre Br Br Br II II IV V a. none of these b. Il and IV c. Il and V d. I and IV e. I only What type of bond cleavage does the following reaction involve? (CH3)3CB → (CH3)3C+ + Br¯ a. lonic b. covalent c. free radical d. heterolytic e. homolytic %3D
Identify the nucleophile in the following reaction:
2R'OH + RX → ROR' + [R'OH2]* + X¯
а. X-
b. RX
c. R'OH
d. ROR'
Which alkyl halide would you expect to react most slowly when heated in aqueous solution?
a. tert-butyl iodide
b. tert-butyl fluoride
c. tert-butyl bromide
d. tert-butyl chloride
Identify the sequence of curved arrows (electron movement) in the steps of the
following reaction.
:Br:
a. loss of leaving group, rearrangement
b. proton transfer, nucleophilic attack
c. loss of leaving group, proton transfer
d. loss of leaving group, nucleophilic attack
Which of the following energy diagrams shows a step-wise endergonic reaction?
reaction coordinate
reaction coordinate
reaction coordinate
а.
b.
c.
d. none of
these
free energy,
kJ/mol
free energy.
kJ/mol
free energy,
kJ/mol
Transcribed Image Text:Identify the nucleophile in the following reaction: 2R'OH + RX → ROR' + [R'OH2]* + X¯ а. X- b. RX c. R'OH d. ROR' Which alkyl halide would you expect to react most slowly when heated in aqueous solution? a. tert-butyl iodide b. tert-butyl fluoride c. tert-butyl bromide d. tert-butyl chloride Identify the sequence of curved arrows (electron movement) in the steps of the following reaction. :Br: a. loss of leaving group, rearrangement b. proton transfer, nucleophilic attack c. loss of leaving group, proton transfer d. loss of leaving group, nucleophilic attack Which of the following energy diagrams shows a step-wise endergonic reaction? reaction coordinate reaction coordinate reaction coordinate а. b. c. d. none of these free energy, kJ/mol free energy. kJ/mol free energy, kJ/mol
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