24. Select the molecule most likely to form an enolate when treated with a sufficiently strong base, such as LDA. HO A B D

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Chapter1: Chemical Foundations
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24. Select the molecule most likely to form an enolate when treated with a
sufficiently strong base, such as LDA.
НО
A
D
25. Select the major product when 7-hydroxyl-2-heptanone is subjected
oxidation with the Jones reagent (sodium dichromate in sulfuric acid
solution).
НО.
HO
HO
A
HO
HO
с
D
26. Identify the major hydrolysis
products when the following
HBr(conc)
ether is reacted with
concentrated HCl:
Br
A
HO
B
Br
+
Br.
НО.
Br
Br
Br
+
Br.
НО.
Br
Br
Transcribed Image Text:24. Select the molecule most likely to form an enolate when treated with a sufficiently strong base, such as LDA. НО A D 25. Select the major product when 7-hydroxyl-2-heptanone is subjected oxidation with the Jones reagent (sodium dichromate in sulfuric acid solution). НО. HO HO A HO HO с D 26. Identify the major hydrolysis products when the following HBr(conc) ether is reacted with concentrated HCl: Br A HO B Br + Br. НО. Br Br Br + Br. НО. Br Br
27. Select the bond that is formed in a Michael addition to a
conjugated carbonyl.
B
а. А
b. В
С. С
d. C or D
28. Determine the kinetic product for the following organic transformation:
HBr, 200 K
Br
ملل ش ش.
Br
Br
B
29. When cyclopentene undergoes electrophilic addition with one of the
following reagent(s), a meso compound results. Select the reagent(s) that
afford(s) the indicated transformation.
а. 1. mCPBA; 2. Нз0+
b. 1. ВНз, ТHF; 2. NaOH, H202
c. 1. Os04; 2. NaHSO3(aq)
С.
d. Brz
Transcribed Image Text:27. Select the bond that is formed in a Michael addition to a conjugated carbonyl. B а. А b. В С. С d. C or D 28. Determine the kinetic product for the following organic transformation: HBr, 200 K Br ملل ش ش. Br Br B 29. When cyclopentene undergoes electrophilic addition with one of the following reagent(s), a meso compound results. Select the reagent(s) that afford(s) the indicated transformation. а. 1. mCPBA; 2. Нз0+ b. 1. ВНз, ТHF; 2. NaOH, H202 c. 1. Os04; 2. NaHSO3(aq) С. d. Brz
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