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Br 1. Mg, ether 2. CO₂ 3. H₂O* omatic alkyl group oxidized into benzoic acid by KMnO4 Ph-R + KMnO4 → Ph-CO₂H KMnO4 eactions idic water oxidized nitriles into carboxylic acid R-CNR- CN H₂O* heat IH. reduces nitrile into amine (R-CH₂NH₂)

Br 1. Mg, ether 2. CO₂ 3. H₂O* omatic alkyl group oxidized into benzoic acid by KMnO4 Ph-R + KMnO4 → Ph-CO₂H KMnO4 eactions idic water oxidized nitriles into carboxylic acid R-CNR- CN H₂O* heat IH. reduces nitrile into amine (R-CH₂NH₂)

Chemistry: Principles and Practice
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter22: Organic Chemistry And Biochemistry
Section: Chapter Questions
Problem 52QE
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Ch 20. Carboxylic Acids and Nitriles Preparation of carboxylic acid - Primary alcohol: to carboxylic acid by strong oxidation reagents such as CrO3 (Secondary alcohol: oxidized to ketone) - Carboxylation of Grignard Reagents (with CO₂) R-MgBr + O=C=O → RCO₂H Br 1. Mg, ether 2. CO₂ 3. H₂O* - Aromatic alkyl group oxidized into benzoic acid by KMnO4 Ph-R + KMnO4 → Ph-CO₂H KMnO4 Nitriles reactions - Acidic water oxidized nitriles into carboxylic acid R-CN → R-CO₂H CN H₂0* heat - LiAlH4 reduces nitrile into amine (R-CH₂NH₂)
Transcribed Image Text:Ch 20. Carboxylic Acids and Nitriles Preparation of carboxylic acid - Primary alcohol: to carboxylic acid by strong oxidation reagents such as CrO3 (Secondary alcohol: oxidized to ketone) - Carboxylation of Grignard Reagents (with CO₂) R-MgBr + O=C=O → RCO₂H Br 1. Mg, ether 2. CO₂ 3. H₂O* - Aromatic alkyl group oxidized into benzoic acid by KMnO4 Ph-R + KMnO4 → Ph-CO₂H KMnO4 Nitriles reactions - Acidic water oxidized nitriles into carboxylic acid R-CN → R-CO₂H CN H₂0* heat - LiAlH4 reduces nitrile into amine (R-CH₂NH₂)
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