eg A. 2g General O, Energy Splitting Diagram H Не Li Be Ne Na Mg Al Si S CI Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te Xe Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg TI Pb Bi Po At Rn You may wish to refer to the Chromium Octahedral Metal Complex diagram as well as the information given here when completing the following statements: The Cr lon contributes [ Select] V 3d electrons to the Cr(acac)g complex which enter orbitals with [ Select ] symmetry. This complex will have a total spin of [Select] This electronic configuration is likely to have [ Select ) Energy H. Cr(III) acac = acaetylacetonate anion Cr(acac), Weak Field Strong Field I < Br < CI < H20 < acac < NH3 < CN¯ < CO An Example Spectrochemical Series The acetylacetonate ligand is a common bidentate (binds in two places) ligand for metal complexes. It is shown here forming an octahedral complex with the Cr3+ metal ion. We have not discussed the Lewis acid/base properties of the (acac) ligand, so l've provided you with its location in an abbreviated spectrochemical series. While the overall symmetry does not match this, for the purposes of this problem we will treat the coordination environment as having O, symmetry.
eg A. 2g General O, Energy Splitting Diagram H Не Li Be Ne Na Mg Al Si S CI Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te Xe Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg TI Pb Bi Po At Rn You may wish to refer to the Chromium Octahedral Metal Complex diagram as well as the information given here when completing the following statements: The Cr lon contributes [ Select] V 3d electrons to the Cr(acac)g complex which enter orbitals with [ Select ] symmetry. This complex will have a total spin of [Select] This electronic configuration is likely to have [ Select ) Energy H. Cr(III) acac = acaetylacetonate anion Cr(acac), Weak Field Strong Field I < Br < CI < H20 < acac < NH3 < CN¯ < CO An Example Spectrochemical Series The acetylacetonate ligand is a common bidentate (binds in two places) ligand for metal complexes. It is shown here forming an octahedral complex with the Cr3+ metal ion. We have not discussed the Lewis acid/base properties of the (acac) ligand, so l've provided you with its location in an abbreviated spectrochemical series. While the overall symmetry does not match this, for the purposes of this problem we will treat the coordination environment as having O, symmetry.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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