Biochar is believed to be a good absorbent for various contaminants. In an isotherm experiment, a series of 20 mL polyethylene centrifuge tubes containing nutrient (NH4Cl) solutions (Volume: 12 mL, pH adjusted to 7.0 ± 0.2) with NH4+-N concentrations of 60, 120, 180, 240, or 480 mg/L and 200 mg of switchgrass biochar samples (sealed with Telflon-line screw caps) were agitated on a wrist action shaker for 24 h (pre-examined to be sufficient) to reach equilibrium. The concentrations of NH4+-N at equilibrium are summarized in the table below. Initial NH4+-N concentration (mg/L) NH4+-N concentration at equilibrium (mg/L) 60 54 120 110 180 165 240 228 480 471   Please use the Freundlich isotherm model to estimate the adsorption constant values of switchgrass biochar

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Biochar is believed to be a good absorbent for various contaminants. In an isotherm experiment, a series of 20 mL polyethylene centrifuge tubes containing nutrient (NH4Cl) solutions (Volume: 12 mL, pH adjusted to 7.0 ± 0.2) with NH4+-N concentrations of 60, 120, 180, 240, or 480 mg/L and 200 mg of switchgrass biochar samples (sealed with Telflon-line screw caps) were agitated on a wrist action shaker for 24 h (pre-examined to be sufficient) to reach equilibrium. The concentrations of NH4+-N at equilibrium are summarized in the table below.

Initial NH4+-N concentration (mg/L)

NH4+-N concentration at equilibrium (mg/L)

60

54

120

110

180

165

240

228

480

471

 

Please use the Freundlich isotherm model to estimate the adsorption constant values of switchgrass biochar.

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