Benzene in Exit Stream (mol %) 1.62 1.31 0.56 0.37 0.24 1.06 0.85 t (s) 50 150 400 300 100 200 500
When the impurity cumene hydroperoxide is present in trace amounts in a cumene feed stream, it can deactivate the silica-alumina catalyst over which cumene is being cracked to form benzene and propylene.The following data were taken at 1 atm and 420oC in a differential reactor. The feed consists of cumene and a trace (0.08 mol %) of cumene hydroperoxide (CHP).(a)Determine the order of decay and the decay constant.
(b)As a first approximation (actually a rather good one), we shall neglect the denominator of the catalytic rate law and consider the reaction to be first order in cumene. Given that the specific reaction rate with respect to cumene is k=3.8x103mol/kg fresh cat.s.atm, the molar flow rate of
cumene (99.92% cumene, 0.08% CHP) is 200 mol/min, the entering concentration is 0.06kmol/m3, the catalyst weight is 100 kg, and the velocity of solids is 1.0 kg/min, what conversion of cumene will be achieved in a moving-bed reactor?
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