Based on the student's observation, calculate the dissolution enthalpy of BaCl,(s) in kJ/mol.

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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**Understanding Dissolution Enthalpy in Chemistry**

When a solid dissolves in water, the resulting solution may experience a temperature change, becoming either hotter or colder. This temperature change is related to the concept of dissolution enthalpy, which can be accurately measured using a coffee cup calorimeter.

**Laboratory Experiment: Dissolution of BaCl₂**

In a laboratory setting, a general chemistry student observed the following during an experiment involving the dissolution of BaCl₂:

- **Mass of BaCl₂**: 17.30 g
- **Mass of water**: 112.70 g
- **Initial temperature of solution**: 24.24 °C
- **Final temperature of solution**: 26.93 °C

This indicates a temperature increase of the solution from 24.24 °C to 26.93 °C.

**Calorimeter Heat Capacity**

The heat capacity of the calorimeter used in this experiment (also referred to as the calorimeter constant) was previously determined to be 1.51 J/°C.

**Calculating Dissolution Enthalpy**

To find the dissolution enthalpy of BaCl₂ in kilojoules per mole (kJ/mol), use the temperature change data along with the heat capacity of the calorimeter. Assume that the specific heat capacity of the solution is equivalent to that of pure water.

**Expression for Dissolution Enthalpy**

Δ_disH = ____ kJ/mol

This field remains to be completed with the calculated value based on the student’s observations and the calorimeter data.
Transcribed Image Text:**Understanding Dissolution Enthalpy in Chemistry** When a solid dissolves in water, the resulting solution may experience a temperature change, becoming either hotter or colder. This temperature change is related to the concept of dissolution enthalpy, which can be accurately measured using a coffee cup calorimeter. **Laboratory Experiment: Dissolution of BaCl₂** In a laboratory setting, a general chemistry student observed the following during an experiment involving the dissolution of BaCl₂: - **Mass of BaCl₂**: 17.30 g - **Mass of water**: 112.70 g - **Initial temperature of solution**: 24.24 °C - **Final temperature of solution**: 26.93 °C This indicates a temperature increase of the solution from 24.24 °C to 26.93 °C. **Calorimeter Heat Capacity** The heat capacity of the calorimeter used in this experiment (also referred to as the calorimeter constant) was previously determined to be 1.51 J/°C. **Calculating Dissolution Enthalpy** To find the dissolution enthalpy of BaCl₂ in kilojoules per mole (kJ/mol), use the temperature change data along with the heat capacity of the calorimeter. Assume that the specific heat capacity of the solution is equivalent to that of pure water. **Expression for Dissolution Enthalpy** Δ_disH = ____ kJ/mol This field remains to be completed with the calculated value based on the student’s observations and the calorimeter data.
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